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Article: Monometallation of a di(aminoaryl) ether induces a Smiles rearrangement leading to a sodium aryloxide complex: The synthesis and crystal structure of [(MeOCH2CH2)(C6H4NHCH 2CH2OMe)NC6H4O·Na] 2

TitleMonometallation of a di(aminoaryl) ether induces a Smiles rearrangement leading to a sodium aryloxide complex: The synthesis and crystal structure of [(MeOCH<inf>2</inf>CH<inf>2</inf>)(C<inf>6</inf>H<inf>4</inf>NHCH <inf>2</inf>CH<inf>2</inf>OMe)NC<inf>6</inf>H<inf>4</inf>O·Na] <inf>2</inf>
Authors
Issue Date1993
Citation
Journal of the Chemical Society, Chemical Communications, 1993, n. 17, p. 1355-1357 How to Cite?
AbstractThe title compound was synthesised by 1: 1 reaction of sodium hydride with a di(aminoaryl) ether ligand in toluene-hexamethylphosphoramide (HMPA) solution; X-ray crystallography revealed that an in situ Smiles rearrangement of the ligand had taken place to give a dimeric aryloxide sodium complex, which is in stark contrast to previous results obtained by 2: 1 reaction of BunLi with the ligand in the absence of HMPA.
Persistent Identifierhttp://hdl.handle.net/10722/332777
ISSN
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorCragg-Hine, Ian-
dc.contributor.authorDavidson, Matthew G.-
dc.contributor.authorKocian, Oldrich-
dc.contributor.authorKottke, Thomas-
dc.contributor.authorMair, Francis S.-
dc.contributor.authorSnaith, Ronald-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:14:12Z-
dc.date.available2023-10-06T05:14:12Z-
dc.date.issued1993-
dc.identifier.citationJournal of the Chemical Society, Chemical Communications, 1993, n. 17, p. 1355-1357-
dc.identifier.issn0022-4936-
dc.identifier.urihttp://hdl.handle.net/10722/332777-
dc.description.abstractThe title compound was synthesised by 1: 1 reaction of sodium hydride with a di(aminoaryl) ether ligand in toluene-hexamethylphosphoramide (HMPA) solution; X-ray crystallography revealed that an in situ Smiles rearrangement of the ligand had taken place to give a dimeric aryloxide sodium complex, which is in stark contrast to previous results obtained by 2: 1 reaction of BunLi with the ligand in the absence of HMPA.-
dc.languageeng-
dc.relation.ispartofJournal of the Chemical Society, Chemical Communications-
dc.titleMonometallation of a di(aminoaryl) ether induces a Smiles rearrangement leading to a sodium aryloxide complex: The synthesis and crystal structure of [(MeOCH<inf>2</inf>CH<inf>2</inf>)(C<inf>6</inf>H<inf>4</inf>NHCH <inf>2</inf>CH<inf>2</inf>OMe)NC<inf>6</inf>H<inf>4</inf>O·Na] <inf>2</inf>-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/C39930001355-
dc.identifier.scopuseid_2-s2.0-37049090539-
dc.identifier.issue17-
dc.identifier.spage1355-
dc.identifier.epage1357-
dc.identifier.isiWOS:A1993LW75000024-

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