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- Publisher Website: 10.1039/c39810000612
- Scopus: eid_2-s2.0-37049091502
- WOS: WOS:A1981LV84200026
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Article: Second-sphere co-ordination of neutral and cationic transition metal complexes by crown ethers
| Title | Second-sphere co-ordination of neutral and cationic transition metal complexes by crown ethers |
|---|---|
| Authors | |
| Issue Date | 1981 |
| Citation | Journal of the Chemical Society, Chemical Communications, 1981, n. 12, p. 612-613 How to Cite? |
| Abstract | The [ammine(η5-cyclopentadienyl)dicarbonyliron(II)] cation and the neutral complex, amminepentacarbonyltungsten(0), form 1:1 adducts in solution with 18-crown-6 and dibenzo-18-crown-6 by virtue of hydrogen bonding between the ammine ligand in the transition metal complex and oxygen atoms of the crown ether; a crystalline adduct, [W(CO)5NH3.dibenzo- 18-crown-6], has been isolated as a benzene solvate. |
| Persistent Identifier | http://hdl.handle.net/10722/332779 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Colquhoun, Howard M. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.date.accessioned | 2023-10-06T05:14:12Z | - |
| dc.date.available | 2023-10-06T05:14:12Z | - |
| dc.date.issued | 1981 | - |
| dc.identifier.citation | Journal of the Chemical Society, Chemical Communications, 1981, n. 12, p. 612-613 | - |
| dc.identifier.issn | 0022-4936 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332779 | - |
| dc.description.abstract | The [ammine(η5-cyclopentadienyl)dicarbonyliron(II)] cation and the neutral complex, amminepentacarbonyltungsten(0), form 1:1 adducts in solution with 18-crown-6 and dibenzo-18-crown-6 by virtue of hydrogen bonding between the ammine ligand in the transition metal complex and oxygen atoms of the crown ether; a crystalline adduct, [W(CO)5NH3.dibenzo- 18-crown-6], has been isolated as a benzene solvate. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of the Chemical Society, Chemical Communications | - |
| dc.title | Second-sphere co-ordination of neutral and cationic transition metal complexes by crown ethers | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1039/c39810000612 | - |
| dc.identifier.scopus | eid_2-s2.0-37049091502 | - |
| dc.identifier.issue | 12 | - |
| dc.identifier.spage | 612 | - |
| dc.identifier.epage | 613 | - |
| dc.identifier.isi | WOS:A1981LV84200026 | - |