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Article: 1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature 1H N.M.R. spectroscopic investigation

Title1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature <sup>1</sup>H N.M.R. spectroscopic investigation
Authors
Issue Date1982
Citation
Journal of the Chemical Society - Series Chemical Communications, 1982, n. 19, p. 1096-1097 How to Cite?
AbstractThe results of variable-temperature 1H n.m.r. spectroscopic investigations, including both multiple irradiation experiments and qualitative measurements of nuclear Overhauser effects, on D-(2)-PhCH2NH3ClO4 indicate that the conformation (Ha/Hc) in which the phenyl ring in the cation is oriented over one of the 1,3-dioxan rings in D-(2) becomes increasingly preferred in CD2Cl2 solution as the temperature is lowered. © The Royal Society of Chemistry, 1982.
Persistent Identifierhttp://hdl.handle.net/10722/332811
ISSN
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorFuller, Steven E.-
dc.contributor.authorMann, Brian E.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:14:27Z-
dc.date.available2023-10-06T05:14:27Z-
dc.date.issued1982-
dc.identifier.citationJournal of the Chemical Society - Series Chemical Communications, 1982, n. 19, p. 1096-1097-
dc.identifier.issn0022-4936-
dc.identifier.urihttp://hdl.handle.net/10722/332811-
dc.description.abstractThe results of variable-temperature 1H n.m.r. spectroscopic investigations, including both multiple irradiation experiments and qualitative measurements of nuclear Overhauser effects, on D-(2)-PhCH2NH3ClO4 indicate that the conformation (Ha/Hc) in which the phenyl ring in the cation is oriented over one of the 1,3-dioxan rings in D-(2) becomes increasingly preferred in CD2Cl2 solution as the temperature is lowered. © The Royal Society of Chemistry, 1982.-
dc.languageeng-
dc.relation.ispartofJournal of the Chemical Society - Series Chemical Communications-
dc.title1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature <sup>1</sup>H N.M.R. spectroscopic investigation-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/C39820001096-
dc.identifier.scopuseid_2-s2.0-37049113633-
dc.identifier.issue19-
dc.identifier.spage1096-
dc.identifier.epage1097-
dc.identifier.isiWOS:A1982PK18500005-

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