File Download
There are no files associated with this item.
Supplementary
-
Citations:
- Scopus: 0
- Appears in Collections:
Article: Towards the stepwise assembly of molecular Borromean Rings. A donor-acceptor ring-in-ring complex
| Title | Towards the stepwise assembly of molecular Borromean Rings. A donor-acceptor ring-in-ring complex |
|---|---|
| Authors | |
| Keywords | Borromean Rings Crystal structure Donor-acceptor Ring-in-ring complex Supramolecular chemistry |
| Issue Date | 2009 |
| Citation | Journal of the Mexican Chemical Society, 2009, v. 53, n. 3, p. 134-138 How to Cite? |
| Abstract | The assembly of molecular Borromean Rings from constitutionally independent rings in a stepwise manner depends on the preparation of robust "gring-in-ring" complexes. The π-electron rich macrocycle bis-1,5-dinaphtho[50]crown-14(1) is shown to form donor-acceptor ring-in-ring complex with the π-electron poor cyclophane cyclobis(paraquat-4,4'- biphenylene) (24+) in solution. In the crystal superstructure of [1⊂2]·4PF6, CH...O interactions between the polyether loops of 1 and the bipyridinium units of 24+ could disfavor the threading of dialkylammonium components of a third ring. © 2009, Sociedad Química de México. |
| Persistent Identifier | http://hdl.handle.net/10722/332919 |
| ISSN | 2021 Impact Factor: 0.869 2020 SCImago Journal Rankings: 0.172 |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Forgan, Ross S. | - |
| dc.contributor.author | Spruell, Jason M. | - |
| dc.contributor.author | Olsen, John Carl | - |
| dc.contributor.author | Stern, Charlotte L. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.date.accessioned | 2023-10-06T05:15:21Z | - |
| dc.date.available | 2023-10-06T05:15:21Z | - |
| dc.date.issued | 2009 | - |
| dc.identifier.citation | Journal of the Mexican Chemical Society, 2009, v. 53, n. 3, p. 134-138 | - |
| dc.identifier.issn | 1870-249X | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332919 | - |
| dc.description.abstract | The assembly of molecular Borromean Rings from constitutionally independent rings in a stepwise manner depends on the preparation of robust "gring-in-ring" complexes. The π-electron rich macrocycle bis-1,5-dinaphtho[50]crown-14(1) is shown to form donor-acceptor ring-in-ring complex with the π-electron poor cyclophane cyclobis(paraquat-4,4'- biphenylene) (24+) in solution. In the crystal superstructure of [1⊂2]·4PF6, CH...O interactions between the polyether loops of 1 and the bipyridinium units of 24+ could disfavor the threading of dialkylammonium components of a third ring. © 2009, Sociedad Química de México. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of the Mexican Chemical Society | - |
| dc.subject | Borromean Rings | - |
| dc.subject | Crystal structure | - |
| dc.subject | Donor-acceptor | - |
| dc.subject | Ring-in-ring complex | - |
| dc.subject | Supramolecular chemistry | - |
| dc.title | Towards the stepwise assembly of molecular Borromean Rings. A donor-acceptor ring-in-ring complex | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.scopus | eid_2-s2.0-77953184137 | - |
| dc.identifier.volume | 53 | - |
| dc.identifier.issue | 3 | - |
| dc.identifier.spage | 134 | - |
| dc.identifier.epage | 138 | - |
| dc.identifier.eissn | 1665-9686 | - |