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Article: Template-directed syntheses of rigid oligorotaxanes under thermodynamic control

TitleTemplate-directed syntheses of rigid oligorotaxanes under thermodynamic control
Authors
Belowich, Matthew E.Valente, CoryStoddart, J. Fraser
KeywordsDynamic covalent chemistry
Mechanically interlocked molecules
Molecular recognition
Noncovalent bonding interactions
Self-assembly
Issue Date2010
Citation
Angewandte Chemie - International Edition, 2010, v. 49, n. 40, p. 7208-7212 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.201004304
AbstractStrategically placing secondary dialkyl-ammonium recognition sites at the magic distance of 3.5 Å apart in the dumbbell components of a series of oligorotaxanes (see picture) renders otherwise conformationally floppy [n]rotaxanes rigid and rodlike. These oligorotaxanes form with near-quantitative conversion under thermodynamic control using dynamic covalent chemistry. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/332922
ISSN
1433-7851
2021 Impact Factor: 16.823
2020 SCImago Journal Rankings: 5.831
ISI Accession Number ID
WOS:000282916800006

 

DC FieldValueLanguage
dc.contributor.authorBelowich, Matthew E.-
dc.contributor.authorValente, Cory-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:15:22Z-
dc.date.available2023-10-06T05:15:22Z-
dc.date.issued2010-
dc.identifier.citationAngewandte Chemie - International Edition, 2010, v. 49, n. 40, p. 7208-7212-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/332922-
dc.description.abstractStrategically placing secondary dialkyl-ammonium recognition sites at the magic distance of 3.5 Å apart in the dumbbell components of a series of oligorotaxanes (see picture) renders otherwise conformationally floppy [n]rotaxanes rigid and rodlike. These oligorotaxanes form with near-quantitative conversion under thermodynamic control using dynamic covalent chemistry. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectDynamic covalent chemistry-
dc.subjectMechanically interlocked molecules-
dc.subjectMolecular recognition-
dc.subjectNoncovalent bonding interactions-
dc.subjectSelf-assembly-
dc.titleTemplate-directed syntheses of rigid oligorotaxanes under thermodynamic control-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201004304-
dc.identifier.scopuseid_2-s2.0-77957357805-
dc.identifier.volume49-
dc.identifier.issue40-
dc.identifier.spage7208-
dc.identifier.epage7212-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:000282916800006-

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