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- Publisher Website: 10.1002/anie.201004304
- Scopus: eid_2-s2.0-77957357805
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Article: Template-directed syntheses of rigid oligorotaxanes under thermodynamic control
Title | Template-directed syntheses of rigid oligorotaxanes under thermodynamic control |
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Authors | |
Keywords | Dynamic covalent chemistry Mechanically interlocked molecules Molecular recognition Noncovalent bonding interactions Self-assembly |
Issue Date | 2010 |
Citation | Angewandte Chemie - International Edition, 2010, v. 49, n. 40, p. 7208-7212 How to Cite? |
Abstract | Strategically placing secondary dialkyl-ammonium recognition sites at the magic distance of 3.5 Å apart in the dumbbell components of a series of oligorotaxanes (see picture) renders otherwise conformationally floppy [n]rotaxanes rigid and rodlike. These oligorotaxanes form with near-quantitative conversion under thermodynamic control using dynamic covalent chemistry. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Persistent Identifier | http://hdl.handle.net/10722/332922 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Belowich, Matthew E. | - |
dc.contributor.author | Valente, Cory | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.date.accessioned | 2023-10-06T05:15:22Z | - |
dc.date.available | 2023-10-06T05:15:22Z | - |
dc.date.issued | 2010 | - |
dc.identifier.citation | Angewandte Chemie - International Edition, 2010, v. 49, n. 40, p. 7208-7212 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10722/332922 | - |
dc.description.abstract | Strategically placing secondary dialkyl-ammonium recognition sites at the magic distance of 3.5 Å apart in the dumbbell components of a series of oligorotaxanes (see picture) renders otherwise conformationally floppy [n]rotaxanes rigid and rodlike. These oligorotaxanes form with near-quantitative conversion under thermodynamic control using dynamic covalent chemistry. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. | - |
dc.language | eng | - |
dc.relation.ispartof | Angewandte Chemie - International Edition | - |
dc.subject | Dynamic covalent chemistry | - |
dc.subject | Mechanically interlocked molecules | - |
dc.subject | Molecular recognition | - |
dc.subject | Noncovalent bonding interactions | - |
dc.subject | Self-assembly | - |
dc.title | Template-directed syntheses of rigid oligorotaxanes under thermodynamic control | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/anie.201004304 | - |
dc.identifier.scopus | eid_2-s2.0-77957357805 | - |
dc.identifier.volume | 49 | - |
dc.identifier.issue | 40 | - |
dc.identifier.spage | 7208 | - |
dc.identifier.epage | 7212 | - |
dc.identifier.eissn | 1521-3773 | - |
dc.identifier.isi | WOS:000282916800006 | - |