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Article: Large-pore apertures in a series of metal-organic frameworks

TitleLarge-pore apertures in a series of metal-organic frameworks
Authors
Issue Date2012
Citation
Science, 2012, v. 336, n. 6084, p. 1018-1023 How to Cite?
AbstractWe report a strategy to expand the pore aperture of metal-organic frameworks (MOFs) into a previously unattained size regime (>32 angstroms). Specifically, the systematic expansion of a well-known MOF structure, MOF-74, from its original link of one phenylene ring (I) to two, three, four, five, six, seven, nine, and eleven (II to XI, respectively), afforded an isoreticular series of MOF-74 structures (termed IRMOF-74-I to XI) with pore apertures ranging from 14 to 98 angstroms. All members of this series have non-interpenetrating structures and exhibit robust architectures, as evidenced by their permanent porosity and high thermal stability (up to 300°C). The pore apertures of an oligoethylene glycol-functionalized IRMOF-74-VII and IRMOF-74-IX are large enough for natural proteins to enter the pores.
Persistent Identifierhttp://hdl.handle.net/10722/332976
ISSN
2023 Impact Factor: 44.7
2023 SCImago Journal Rankings: 11.902
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorDeng, Hexiang-
dc.contributor.authorGrunder, Sergio-
dc.contributor.authorCordova, Kyle E.-
dc.contributor.authorValente, Cory-
dc.contributor.authorFurukawa, Hiroyasu-
dc.contributor.authorHmadeh, Mohamad-
dc.contributor.authorGándara, Felipe-
dc.contributor.authorWhalley, Adam C.-
dc.contributor.authorLiu, Zheng-
dc.contributor.authorAsahina, Shunsuke-
dc.contributor.authorKazumori, Hiroyoshi-
dc.contributor.authorO'Keeffe, Michael-
dc.contributor.authorTerasaki, Osamu-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorYaghi, Omar M.-
dc.date.accessioned2023-10-06T05:15:47Z-
dc.date.available2023-10-06T05:15:47Z-
dc.date.issued2012-
dc.identifier.citationScience, 2012, v. 336, n. 6084, p. 1018-1023-
dc.identifier.issn0036-8075-
dc.identifier.urihttp://hdl.handle.net/10722/332976-
dc.description.abstractWe report a strategy to expand the pore aperture of metal-organic frameworks (MOFs) into a previously unattained size regime (>32 angstroms). Specifically, the systematic expansion of a well-known MOF structure, MOF-74, from its original link of one phenylene ring (I) to two, three, four, five, six, seven, nine, and eleven (II to XI, respectively), afforded an isoreticular series of MOF-74 structures (termed IRMOF-74-I to XI) with pore apertures ranging from 14 to 98 angstroms. All members of this series have non-interpenetrating structures and exhibit robust architectures, as evidenced by their permanent porosity and high thermal stability (up to 300°C). The pore apertures of an oligoethylene glycol-functionalized IRMOF-74-VII and IRMOF-74-IX are large enough for natural proteins to enter the pores.-
dc.languageeng-
dc.relation.ispartofScience-
dc.titleLarge-pore apertures in a series of metal-organic frameworks-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1126/science.1220131-
dc.identifier.scopuseid_2-s2.0-84861452693-
dc.identifier.volume336-
dc.identifier.issue6084-
dc.identifier.spage1018-
dc.identifier.epage1023-
dc.identifier.eissn1095-9203-
dc.identifier.isiWOS:000304406800041-

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