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Article: Synthesis, structure, and metalation of two new highly porous zirconium metal-organic frameworks

TitleSynthesis, structure, and metalation of two new highly porous zirconium metal-organic frameworks
Authors
Issue Date2012
Citation
Inorganic Chemistry, 2012, v. 51, n. 12, p. 6443-6445 How to Cite?
AbstractThree new metal-organic frameworks [MOF-525, Zr 6O 4(OH) 4(TCPP-H 2) 3; MOF-535, Zr 6O 4(OH) 4(XF) 3; MOF-545, Zr 6O 8(H 2O) 8(TCPP-H 2) 2, where porphyrin H 4-TCPP-H 2 = (C 48H 24O 8N 4) and cruciform H 4-XF = (C 42O 8H 22)] based on two new topologies, ftw and csq, have been synthesized and structurally characterized. MOF-525 and -535 are composed of Zr 6O 4(OH) 4 cuboctahedral units linked by either porphyrin (MOF-525) or cruciform (MOF-535). Another zirconium-containing unit, Zr 6O 8(H 2O) 8, is linked by porphyrin to give the MOF-545 structure. The structure of MOF-525 was obtained by analysis of powder X-ray diffraction data. The structures of MOF-535 and -545 were resolved from synchrotron single-crystal data. MOF-525, -535, and -545 have Brunauer-Emmett-Teller surface areas of 2620, 1120, and 2260 m 2/g, respectively. In addition to their large surface areas, both porphyrin-containing MOFs are exceptionally chemically stable, maintaining their structures under aqueous and organic conditions. MOF-525 and -545 were metalated with iron(III) and copper(II) to yield the metalated analogues without losing their high surface area and chemical stability. © 2012 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/332979
ISSN
2023 Impact Factor: 4.3
2023 SCImago Journal Rankings: 0.928
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorMorris, William-
dc.contributor.authorVolosskiy, Boris-
dc.contributor.authorDemir, Selcuk-
dc.contributor.authorGándara, Felipe-
dc.contributor.authorMcGrier, Psaras L.-
dc.contributor.authorFurukawa, Hiroyasu-
dc.contributor.authorCascio, Duilio-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorYaghi, Omar M.-
dc.date.accessioned2023-10-06T05:15:48Z-
dc.date.available2023-10-06T05:15:48Z-
dc.date.issued2012-
dc.identifier.citationInorganic Chemistry, 2012, v. 51, n. 12, p. 6443-6445-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10722/332979-
dc.description.abstractThree new metal-organic frameworks [MOF-525, Zr 6O 4(OH) 4(TCPP-H 2) 3; MOF-535, Zr 6O 4(OH) 4(XF) 3; MOF-545, Zr 6O 8(H 2O) 8(TCPP-H 2) 2, where porphyrin H 4-TCPP-H 2 = (C 48H 24O 8N 4) and cruciform H 4-XF = (C 42O 8H 22)] based on two new topologies, ftw and csq, have been synthesized and structurally characterized. MOF-525 and -535 are composed of Zr 6O 4(OH) 4 cuboctahedral units linked by either porphyrin (MOF-525) or cruciform (MOF-535). Another zirconium-containing unit, Zr 6O 8(H 2O) 8, is linked by porphyrin to give the MOF-545 structure. The structure of MOF-525 was obtained by analysis of powder X-ray diffraction data. The structures of MOF-535 and -545 were resolved from synchrotron single-crystal data. MOF-525, -535, and -545 have Brunauer-Emmett-Teller surface areas of 2620, 1120, and 2260 m 2/g, respectively. In addition to their large surface areas, both porphyrin-containing MOFs are exceptionally chemically stable, maintaining their structures under aqueous and organic conditions. MOF-525 and -545 were metalated with iron(III) and copper(II) to yield the metalated analogues without losing their high surface area and chemical stability. © 2012 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofInorganic Chemistry-
dc.titleSynthesis, structure, and metalation of two new highly porous zirconium metal-organic frameworks-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic300825s-
dc.identifier.pmid22676251-
dc.identifier.scopuseid_2-s2.0-84862585461-
dc.identifier.volume51-
dc.identifier.issue12-
dc.identifier.spage6443-
dc.identifier.epage6445-
dc.identifier.isiWOS:000305314500007-

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