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Article: Highly efficient ultrafast electron injection from the singlet MLCT excited state of copper(I) diimine complexes to TiO2 nanoparticles

TitleHighly efficient ultrafast electron injection from the singlet MLCT excited state of copper(I) diimine complexes to TiO<inf>2</inf> nanoparticles
Authors
Huang, JierBuyukcakir, OnurMara, Michael W.Coskun, AliDimitrijevic, Nada M.Barin, GokhanKokhan, OleksandrStickrath, Andrew B.Ruppert, RomainTiede, David M.Stoddart, J. FraserSauvage, Jean PierreChen, Lin X.
Keywordscharge transfer
complexes
copper
nanoparticles
structural dynamics
Issue Date2012
Citation
Angewandte Chemie - International Edition, 2012, v. 51, n. 51, p. 12711-12715 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.201204341
AbstractCu complexes as photosensitizers: Photoinduced charge-transfer dynamics from a copper(I) diimine complex to TiO2 nanoparticles were investigated by combining multiple time-resolved spectroscopic methods. An efficient and ultrafast electron transfer process from the singlet MLCT state was discovered as a result of structural control owing to the flattening of the tetrahedral geometry in the complex and the bulky groups in the ligands. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/333012
ISSN
1433-7851
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID
WOS:000312305400010

 

DC FieldValueLanguage
dc.contributor.authorHuang, Jier-
dc.contributor.authorBuyukcakir, Onur-
dc.contributor.authorMara, Michael W.-
dc.contributor.authorCoskun, Ali-
dc.contributor.authorDimitrijevic, Nada M.-
dc.contributor.authorBarin, Gokhan-
dc.contributor.authorKokhan, Oleksandr-
dc.contributor.authorStickrath, Andrew B.-
dc.contributor.authorRuppert, Romain-
dc.contributor.authorTiede, David M.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorSauvage, Jean Pierre-
dc.contributor.authorChen, Lin X.-
dc.date.accessioned2023-10-06T05:16:05Z-
dc.date.available2023-10-06T05:16:05Z-
dc.date.issued2012-
dc.identifier.citationAngewandte Chemie - International Edition, 2012, v. 51, n. 51, p. 12711-12715-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/333012-
dc.description.abstractCu complexes as photosensitizers: Photoinduced charge-transfer dynamics from a copper(I) diimine complex to TiO2 nanoparticles were investigated by combining multiple time-resolved spectroscopic methods. An efficient and ultrafast electron transfer process from the singlet MLCT state was discovered as a result of structural control owing to the flattening of the tetrahedral geometry in the complex and the bulky groups in the ligands. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectcharge transfer-
dc.subjectcomplexes-
dc.subjectcopper-
dc.subjectnanoparticles-
dc.subjectstructural dynamics-
dc.titleHighly efficient ultrafast electron injection from the singlet MLCT excited state of copper(I) diimine complexes to TiO<inf>2</inf> nanoparticles-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201204341-
dc.identifier.scopuseid_2-s2.0-84870991480-
dc.identifier.volume51-
dc.identifier.issue51-
dc.identifier.spage12711-
dc.identifier.epage12715-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:000312305400010-

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