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- Publisher Website: 10.1021/ja3125004
- Scopus: eid_2-s2.0-84874026680
- WOS: WOS:000315373000018
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Article: Redox-controlled selective docking in a [2]catenane host
Title | Redox-controlled selective docking in a [2]catenane host |
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Authors | |
Issue Date | 2013 |
Citation | Journal of the American Chemical Society, 2013, v. 135, n. 7, p. 2466-2469 How to Cite? |
Abstract | The docking by neutral and charged guests selectively in two geometrically different binding pockets in a dynamic [2]catenane host is demonstrated in the solid state by manipulating its redox chemistry. The change in redox properties, not only alters the affinity of the host toward neutral and charged guests, but it also induces a profound change in the geometry of the host to accommodate them. X-ray crystallography, performed on the two different 1:1 complexes, demonstrates unambiguously the fact that the [2]catenane host provides a uniquely different binding pocket wherein a methyl viologen dication is stabilized by interacting with a bipyridinium radical cation, despite the presence of Coulombic repulsions. © 2013 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/333019 |
ISSN | 2023 Impact Factor: 14.4 2023 SCImago Journal Rankings: 5.489 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Barin, Gokhan | - |
dc.contributor.author | Frasconi, Marco | - |
dc.contributor.author | Dyar, Scott M. | - |
dc.contributor.author | Iehl, Julien | - |
dc.contributor.author | Buyukcakir, Onur | - |
dc.contributor.author | Sarjeant, Amy A. | - |
dc.contributor.author | Carmieli, Raanan | - |
dc.contributor.author | Coskun, Ali | - |
dc.contributor.author | Wasielewski, Michael R. | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.date.accessioned | 2023-10-06T05:16:08Z | - |
dc.date.available | 2023-10-06T05:16:08Z | - |
dc.date.issued | 2013 | - |
dc.identifier.citation | Journal of the American Chemical Society, 2013, v. 135, n. 7, p. 2466-2469 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10722/333019 | - |
dc.description.abstract | The docking by neutral and charged guests selectively in two geometrically different binding pockets in a dynamic [2]catenane host is demonstrated in the solid state by manipulating its redox chemistry. The change in redox properties, not only alters the affinity of the host toward neutral and charged guests, but it also induces a profound change in the geometry of the host to accommodate them. X-ray crystallography, performed on the two different 1:1 complexes, demonstrates unambiguously the fact that the [2]catenane host provides a uniquely different binding pocket wherein a methyl viologen dication is stabilized by interacting with a bipyridinium radical cation, despite the presence of Coulombic repulsions. © 2013 American Chemical Society. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of the American Chemical Society | - |
dc.title | Redox-controlled selective docking in a [2]catenane host | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/ja3125004 | - |
dc.identifier.scopus | eid_2-s2.0-84874026680 | - |
dc.identifier.volume | 135 | - |
dc.identifier.issue | 7 | - |
dc.identifier.spage | 2466 | - |
dc.identifier.epage | 2469 | - |
dc.identifier.eissn | 1520-5126 | - |
dc.identifier.isi | WOS:000315373000018 | - |