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Article: Aromatizing olefin metathesis by ligand isolation inside a metal- organic framework

TitleAromatizing olefin metathesis by ligand isolation inside a metal- organic framework
Authors
Issue Date2013
Citation
Journal of the American Chemical Society, 2013, v. 135, n. 40, p. 14916-14919 How to Cite?
AbstractThe aromatizing ring-closing metathesis has been shown to take place inside an extended porous framework. Employing a combination of solvent-assisted linker exchange and postsynthesis modification using olefin metathesis, the noninterpenetrated SALEM-14 was formed and converted catalytically into PAH-MOF-1 with polycyclic aromatic hydrocarbon (PAH) pillars. The metal-organic framework in SALEM-14 prevents "intermolecular" olefin metathesis from occurring between the pillars in the presence of the first generation Hoveyda-Grubbs catalyst, while favoring the production of a PAH, which can be released from the framework under acidic conditions in dimethylsulfoxide. © 2013 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/333045
ISSN
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorVermeulen, Nicolaas A.-
dc.contributor.authorKaragiaridi, Olga-
dc.contributor.authorSarjeant, Amy A.-
dc.contributor.authorStern, Charlotte L.-
dc.contributor.authorHupp, Joseph T.-
dc.contributor.authorFarha, Omar K.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:16:19Z-
dc.date.available2023-10-06T05:16:19Z-
dc.date.issued2013-
dc.identifier.citationJournal of the American Chemical Society, 2013, v. 135, n. 40, p. 14916-14919-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/333045-
dc.description.abstractThe aromatizing ring-closing metathesis has been shown to take place inside an extended porous framework. Employing a combination of solvent-assisted linker exchange and postsynthesis modification using olefin metathesis, the noninterpenetrated SALEM-14 was formed and converted catalytically into PAH-MOF-1 with polycyclic aromatic hydrocarbon (PAH) pillars. The metal-organic framework in SALEM-14 prevents "intermolecular" olefin metathesis from occurring between the pillars in the presence of the first generation Hoveyda-Grubbs catalyst, while favoring the production of a PAH, which can be released from the framework under acidic conditions in dimethylsulfoxide. © 2013 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleAromatizing olefin metathesis by ligand isolation inside a metal- organic framework-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja407333q-
dc.identifier.scopuseid_2-s2.0-84885586612-
dc.identifier.volume135-
dc.identifier.issue40-
dc.identifier.spage14916-
dc.identifier.epage14919-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000326356400006-

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