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Article: A hafnium-based metal-organic framework as an efficient and multifunctional catalyst for facile CO2 fixation and regioselective and enantioretentive epoxide activation

TitleA hafnium-based metal-organic framework as an efficient and multifunctional catalyst for facile CO<inf>2</inf> fixation and regioselective and enantioretentive epoxide activation
Authors
Issue Date2014
Citation
Journal of the American Chemical Society, 2014, v. 136, n. 45, p. 15861-15864 How to Cite?
AbstractPorous heterogeneous catalysts play a pivotal role in the chemical industry. Herein a new Hf-based metal-organic framework (Hf-NU-1000) incorporating Hf6 clusters is reported. It demonstrates high catalytic efficiency for the activation of epoxides, facilitating the quantitative chemical fixation of CO2 into five-membered cyclic carbonates under ambient conditions, rendering this material an excellent catalyst. As a multifunctional catalyst, Hf-NU-1000 is also efficient for other epoxide activations, leading to the regioselective and enantioretentive formation of 1,2-bifuctionalized systems via solvolytic nucleophilic ring opening.
Persistent Identifierhttp://hdl.handle.net/10722/333094
ISSN
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorBeyzavi, M. Hassan-
dc.contributor.authorKlet, Rachel C.-
dc.contributor.authorTussupbayev, Samat-
dc.contributor.authorBorycz, Joshua-
dc.contributor.authorVermeulen, Nicolaas A.-
dc.contributor.authorCramer, Christopher J.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorHupp, Joseph T.-
dc.contributor.authorFarha, Omar K.-
dc.date.accessioned2023-10-06T05:16:42Z-
dc.date.available2023-10-06T05:16:42Z-
dc.date.issued2014-
dc.identifier.citationJournal of the American Chemical Society, 2014, v. 136, n. 45, p. 15861-15864-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/333094-
dc.description.abstractPorous heterogeneous catalysts play a pivotal role in the chemical industry. Herein a new Hf-based metal-organic framework (Hf-NU-1000) incorporating Hf6 clusters is reported. It demonstrates high catalytic efficiency for the activation of epoxides, facilitating the quantitative chemical fixation of CO2 into five-membered cyclic carbonates under ambient conditions, rendering this material an excellent catalyst. As a multifunctional catalyst, Hf-NU-1000 is also efficient for other epoxide activations, leading to the regioselective and enantioretentive formation of 1,2-bifuctionalized systems via solvolytic nucleophilic ring opening.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleA hafnium-based metal-organic framework as an efficient and multifunctional catalyst for facile CO<inf>2</inf> fixation and regioselective and enantioretentive epoxide activation-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja508626n-
dc.identifier.scopuseid_2-s2.0-84910020649-
dc.identifier.volume136-
dc.identifier.issue45-
dc.identifier.spage15861-
dc.identifier.epage15864-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000344906100014-

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