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Article: Activation-Enabled Syntheses of Functionalized Pillar[5]arene Derivatives

TitleActivation-Enabled Syntheses of Functionalized Pillar[5]arene Derivatives
Authors
Issue Date2015
Citation
Organic Letters, 2015, v. 17, n. 13, p. 3260-3263 How to Cite?
AbstractA series of regioselective di- and trifunctionalized pillar[5]arene derivatives have been synthesized by a deprotection-followed-by-activation strategy, and their constitutions have been established as a result of having access to their solid-state structures. De-O-methylation occurs in a stepwise manner at lower temperatures under kinetic control, affording the desired oligo-substituted pillar[5]arene derivatives. In addition, the regioisomers of these derivatives can be isolated by installing triflate groups on the free hydroxyl groups. (Chemical Equation Presented).
Persistent Identifierhttp://hdl.handle.net/10722/333127
ISSN
2023 Impact Factor: 4.9
2023 SCImago Journal Rankings: 1.245
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHan, Jie-
dc.contributor.authorHou, Xisen-
dc.contributor.authorKe, Chenfeng-
dc.contributor.authorZhang, Huacheng-
dc.contributor.authorStrutt, Nathan L.-
dc.contributor.authorStern, Charlotte L.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:16:56Z-
dc.date.available2023-10-06T05:16:56Z-
dc.date.issued2015-
dc.identifier.citationOrganic Letters, 2015, v. 17, n. 13, p. 3260-3263-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10722/333127-
dc.description.abstractA series of regioselective di- and trifunctionalized pillar[5]arene derivatives have been synthesized by a deprotection-followed-by-activation strategy, and their constitutions have been established as a result of having access to their solid-state structures. De-O-methylation occurs in a stepwise manner at lower temperatures under kinetic control, affording the desired oligo-substituted pillar[5]arene derivatives. In addition, the regioisomers of these derivatives can be isolated by installing triflate groups on the free hydroxyl groups. (Chemical Equation Presented).-
dc.languageeng-
dc.relation.ispartofOrganic Letters-
dc.titleActivation-Enabled Syntheses of Functionalized Pillar[5]arene Derivatives-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/acs.orglett.5b01418-
dc.identifier.scopuseid_2-s2.0-84935049339-
dc.identifier.volume17-
dc.identifier.issue13-
dc.identifier.spage3260-
dc.identifier.epage3263-
dc.identifier.eissn1523-7052-
dc.identifier.isiWOS:000357623900019-

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