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Article: Concurrent Covalent and Supramolecular Polymerization

TitleConcurrent Covalent and Supramolecular Polymerization
Authors
Keywordsazide–alkyne cycloaddition
pi interactions
polymerization
supramolecular chemistry
Issue Date2016
Citation
Chemistry - A European Journal, 2016, v. 22, n. 35, p. 12301-12306 How to Cite?
AbstractCovalent and supramolecular polymerizations, both of which offer their own unique advantages, have emerged as popular strategies for making artificial materials. Herein, we describe a concurrent covalent and supramolecular polymerization strategy—namely, one which utilizes 1) a bis-azide-functionalized diazaperopyrenium dication that undergoes polymeriation covalently with a bis-alkyne-functionalized biphenyl derivative in one dimension as a result of a rapid and efficient β-cyclodextrin(CD)-accelerated, cucurbit[6]uril(CB)-templated azide–alkyne cycloaddition, while 2) the aromatic core of the dication is able to dimerize in a criss-cross fashion by dint of π–π interactions, enabling simultaneous supramolecular assembly, resulting in an extended polymer network in an orthogonal dimension.
Persistent Identifierhttp://hdl.handle.net/10722/333186
ISSN
2023 Impact Factor: 3.9
2023 SCImago Journal Rankings: 1.058
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHou, Xisen-
dc.contributor.authorKe, Chenfeng-
dc.contributor.authorZhou, Yu-
dc.contributor.authorXie, Zhuang-
dc.contributor.authorAlngadh, Ahmed-
dc.contributor.authorKeane, Denis T.-
dc.contributor.authorNassar, Majed S.-
dc.contributor.authorBotros, Youssry Y.-
dc.contributor.authorMirkin, Chad A.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:17:22Z-
dc.date.available2023-10-06T05:17:22Z-
dc.date.issued2016-
dc.identifier.citationChemistry - A European Journal, 2016, v. 22, n. 35, p. 12301-12306-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10722/333186-
dc.description.abstractCovalent and supramolecular polymerizations, both of which offer their own unique advantages, have emerged as popular strategies for making artificial materials. Herein, we describe a concurrent covalent and supramolecular polymerization strategy—namely, one which utilizes 1) a bis-azide-functionalized diazaperopyrenium dication that undergoes polymeriation covalently with a bis-alkyne-functionalized biphenyl derivative in one dimension as a result of a rapid and efficient β-cyclodextrin(CD)-accelerated, cucurbit[6]uril(CB)-templated azide–alkyne cycloaddition, while 2) the aromatic core of the dication is able to dimerize in a criss-cross fashion by dint of π–π interactions, enabling simultaneous supramolecular assembly, resulting in an extended polymer network in an orthogonal dimension.-
dc.languageeng-
dc.relation.ispartofChemistry - A European Journal-
dc.subjectazide–alkyne cycloaddition-
dc.subjectpi interactions-
dc.subjectpolymerization-
dc.subjectsupramolecular chemistry-
dc.titleConcurrent Covalent and Supramolecular Polymerization-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/chem.201602954-
dc.identifier.scopuseid_2-s2.0-84978933964-
dc.identifier.volume22-
dc.identifier.issue35-
dc.identifier.spage12301-
dc.identifier.epage12306-
dc.identifier.eissn1521-3765-
dc.identifier.isiWOS:000382876500013-

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