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- Publisher Website: 10.1002/anie.198402351
- Scopus: eid_2-s2.0-84985524329
- WOS: WOS:A1984SP25200010
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Article: Second Sphere Coordination of Cationic Rhodium Complexes by Dibenzo[3n]crown‐n Ethers
Title | Second Sphere Coordination of Cationic Rhodium Complexes by Dibenzo[3n]crown‐n Ethers |
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Authors | |
Issue Date | 1984 |
Citation | Angewandte Chemie International Edition in English, 1984, v. 23, n. 3, p. 235-236 How to Cite? |
Abstract | An unexpected spatial arrangement of the ligands has been observed in the 1 : 1 complexes of [Rh(L)(NH3)2]⊕ with dibenzo[24]crown‐8 as well as dibenzo[30]crown‐10 (L = cyclooctadiene or norbornadiene). The ligands are sandwiched between the two benzene rings of the receptor molecule. The stabilization presumably arise, above all, from [NH…O] hydrogen bonding and other electrostatic interactions. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany |
Persistent Identifier | http://hdl.handle.net/10722/333206 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Colquhoun, Howard M. | - |
dc.contributor.author | Doughty, Simon M. | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.contributor.author | Williams, David J. | - |
dc.date.accessioned | 2023-10-06T05:17:31Z | - |
dc.date.available | 2023-10-06T05:17:31Z | - |
dc.date.issued | 1984 | - |
dc.identifier.citation | Angewandte Chemie International Edition in English, 1984, v. 23, n. 3, p. 235-236 | - |
dc.identifier.issn | 0570-0833 | - |
dc.identifier.uri | http://hdl.handle.net/10722/333206 | - |
dc.description.abstract | An unexpected spatial arrangement of the ligands has been observed in the 1 : 1 complexes of [Rh(L)(NH3)2]⊕ with dibenzo[24]crown‐8 as well as dibenzo[30]crown‐10 (L = cyclooctadiene or norbornadiene). The ligands are sandwiched between the two benzene rings of the receptor molecule. The stabilization presumably arise, above all, from [NH…O] hydrogen bonding and other electrostatic interactions. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany | - |
dc.language | eng | - |
dc.relation.ispartof | Angewandte Chemie International Edition in English | - |
dc.title | Second Sphere Coordination of Cationic Rhodium Complexes by Dibenzo[3n]crown‐n Ethers | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/anie.198402351 | - |
dc.identifier.scopus | eid_2-s2.0-84985524329 | - |
dc.identifier.volume | 23 | - |
dc.identifier.issue | 3 | - |
dc.identifier.spage | 235 | - |
dc.identifier.epage | 236 | - |
dc.identifier.eissn | 1521-3773 | - |
dc.identifier.isi | WOS:A1984SP25200010 | - |