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- Publisher Website: 10.1002/anie.198910441
- Scopus: eid_2-s2.0-84990165959
- WOS: WOS:A1989AN46800024
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Article: A New Coordinating Chiral Lithium Amide
| Title | A New Coordinating Chiral Lithium Amide |
|---|---|
| Authors | |
| Issue Date | 1989 |
| Citation | Angewandte Chemie International Edition in English, 1989, v. 28, n. 8, p. 1044-1047 How to Cite? |
| Abstract | The C2‐symmetric (R,R)‐di(α‐methoxymethylbenzyl)amine 1, synthesized from (R)‐phenylglycinol and α‐methoxyacetophenone, yields a lithium amide 2 upon lithiation with nBuLi. In the solid state and in solution, 2 is present as a dimer. 4‐tert‐Butylcyclohexanone could be asymmetrically deprotonated with this lithium amide. (Figure Presented.) Copyright © 1989 by VCH Verlagsgesellschaft mbH, Germany |
| Persistent Identifier | http://hdl.handle.net/10722/333232 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Barr, Donald | - |
| dc.contributor.author | Berrisford, David J. | - |
| dc.contributor.author | Jones, Raymond V.H. | - |
| dc.contributor.author | Slawin, Alexandra M.Z. | - |
| dc.contributor.author | Snaith, Ronald | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.contributor.author | Williams, David J. | - |
| dc.date.accessioned | 2023-10-06T05:17:43Z | - |
| dc.date.available | 2023-10-06T05:17:43Z | - |
| dc.date.issued | 1989 | - |
| dc.identifier.citation | Angewandte Chemie International Edition in English, 1989, v. 28, n. 8, p. 1044-1047 | - |
| dc.identifier.issn | 0570-0833 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/333232 | - |
| dc.description.abstract | The C2‐symmetric (R,R)‐di(α‐methoxymethylbenzyl)amine 1, synthesized from (R)‐phenylglycinol and α‐methoxyacetophenone, yields a lithium amide 2 upon lithiation with nBuLi. In the solid state and in solution, 2 is present as a dimer. 4‐tert‐Butylcyclohexanone could be asymmetrically deprotonated with this lithium amide. (Figure Presented.) Copyright © 1989 by VCH Verlagsgesellschaft mbH, Germany | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie International Edition in English | - |
| dc.title | A New Coordinating Chiral Lithium Amide | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.198910441 | - |
| dc.identifier.scopus | eid_2-s2.0-84990165959 | - |
| dc.identifier.volume | 28 | - |
| dc.identifier.issue | 8 | - |
| dc.identifier.spage | 1044 | - |
| dc.identifier.epage | 1047 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:A1989AN46800024 | - |