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Article: An efficient artificial molecular pump

TitleAn efficient artificial molecular pump
Authors
KeywordsArtificial molecular machines
Energy ratchet
Non-equilibrium processes
Redox chemistry
Rotaxanes
Issue Date2017
Citation
Tetrahedron, 2017, v. 73, n. 33, p. 4849-4857 How to Cite?
AbstractDespite the fact that artificial molecular machines are on the rise, there is a long way to go to eventually fill the yawning gap that exists between biological and man-made machines in terms of both their mechanisms of action and efficiencies of operation. Herein, we describe our recent efforts directed towards the development of a second-generation (more efficient) artificial molecular pump – a wholly synthetic compound, which operates to compartmentalise highly charged rings in a high-energy state on an oligomethylene chain. The optimized artificial molecular pump operates rapidly, thanks to well-tuned noncovalent bonding interactions, paving the way to address enthalpically and entropically demanding polymers that would be difficult to obtain with the available repertoire of synthetic methods.
Persistent Identifierhttp://hdl.handle.net/10722/333279
ISSN
2023 Impact Factor: 2.1
2023 SCImago Journal Rankings: 0.406
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorPezzato, Cristian-
dc.contributor.authorNguyen, Minh T.-
dc.contributor.authorCheng, Chuyang-
dc.contributor.authorKim, Dong Jun-
dc.contributor.authorOtley, Michael T.-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:18:08Z-
dc.date.available2023-10-06T05:18:08Z-
dc.date.issued2017-
dc.identifier.citationTetrahedron, 2017, v. 73, n. 33, p. 4849-4857-
dc.identifier.issn0040-4020-
dc.identifier.urihttp://hdl.handle.net/10722/333279-
dc.description.abstractDespite the fact that artificial molecular machines are on the rise, there is a long way to go to eventually fill the yawning gap that exists between biological and man-made machines in terms of both their mechanisms of action and efficiencies of operation. Herein, we describe our recent efforts directed towards the development of a second-generation (more efficient) artificial molecular pump – a wholly synthetic compound, which operates to compartmentalise highly charged rings in a high-energy state on an oligomethylene chain. The optimized artificial molecular pump operates rapidly, thanks to well-tuned noncovalent bonding interactions, paving the way to address enthalpically and entropically demanding polymers that would be difficult to obtain with the available repertoire of synthetic methods.-
dc.languageeng-
dc.relation.ispartofTetrahedron-
dc.subjectArtificial molecular machines-
dc.subjectEnergy ratchet-
dc.subjectNon-equilibrium processes-
dc.subjectRedox chemistry-
dc.subjectRotaxanes-
dc.titleAn efficient artificial molecular pump-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.tet.2017.05.087-
dc.identifier.scopuseid_2-s2.0-85020436629-
dc.identifier.volume73-
dc.identifier.issue33-
dc.identifier.spage4849-
dc.identifier.epage4857-
dc.identifier.eissn1464-5416-
dc.identifier.isiWOS:000407524400004-

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