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Article: Electron / hole catalysis: A versatile strategy for promoting chemical transformations

TitleElectron / hole catalysis: A versatile strategy for promoting chemical transformations
Authors
KeywordsCatalysis
Electrochemistry
Electron transfer
Mechanochemistry
Photochemistry
Supramolecular chemistry
Issue Date2022
Citation
Tetrahedron, 2022, v. 126, article no. 133065 How to Cite?
AbstractElectron transfer is a fundamental chemical process that adds an electron into one chemical entity and generates a hole in another. Both the additional electron and the corresponding hole exhibit remarkable catalytic effects in promoting chemical transformations. In this Perspective, by classifying the implementation methods of electron/hole catalysis into four categories—namely, chemical, electrochemical, photochemical and mechanochemical means—we summarize the recent progress in this burgeoning field of research, focusing on the elegant ways that have been developed to inject or remove electrons into or from reaction systems under mild conditions. Moreover, recent advances in research involving the applications of electron/hole catalysis in molecular switches and supramolecular assemblies are also highlighted in order to show the versatility and potential of this strategy in all aspects of contemporary chemistry including, but not limited to, organic synthesis.
Persistent Identifierhttp://hdl.handle.net/10722/333561
ISSN
2023 Impact Factor: 2.1
2023 SCImago Journal Rankings: 0.406
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorJiao, Yang-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:20:36Z-
dc.date.available2023-10-06T05:20:36Z-
dc.date.issued2022-
dc.identifier.citationTetrahedron, 2022, v. 126, article no. 133065-
dc.identifier.issn0040-4020-
dc.identifier.urihttp://hdl.handle.net/10722/333561-
dc.description.abstractElectron transfer is a fundamental chemical process that adds an electron into one chemical entity and generates a hole in another. Both the additional electron and the corresponding hole exhibit remarkable catalytic effects in promoting chemical transformations. In this Perspective, by classifying the implementation methods of electron/hole catalysis into four categories—namely, chemical, electrochemical, photochemical and mechanochemical means—we summarize the recent progress in this burgeoning field of research, focusing on the elegant ways that have been developed to inject or remove electrons into or from reaction systems under mild conditions. Moreover, recent advances in research involving the applications of electron/hole catalysis in molecular switches and supramolecular assemblies are also highlighted in order to show the versatility and potential of this strategy in all aspects of contemporary chemistry including, but not limited to, organic synthesis.-
dc.languageeng-
dc.relation.ispartofTetrahedron-
dc.subjectCatalysis-
dc.subjectElectrochemistry-
dc.subjectElectron transfer-
dc.subjectMechanochemistry-
dc.subjectPhotochemistry-
dc.subjectSupramolecular chemistry-
dc.titleElectron / hole catalysis: A versatile strategy for promoting chemical transformations-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.tet.2022.133065-
dc.identifier.scopuseid_2-s2.0-85139731718-
dc.identifier.volume126-
dc.identifier.spagearticle no. 133065-
dc.identifier.epagearticle no. 133065-
dc.identifier.eissn1464-5416-
dc.identifier.isiWOS:000917087100013-

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