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- Publisher Website: 10.1002/anie.200250453
- Scopus: eid_2-s2.0-0037418978
- WOS: WOS:000182337000008
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Article: Toward chemically controlled nanoscale molecular machinery
| Title | Toward chemically controlled nanoscale molecular machinery |
|---|---|
| Authors | |
| Keywords | Chemical switching Molecular devices Rotaxanes self-assembly Supramolecular chemistry |
| Issue Date | 2003 |
| Citation | Angewandte Chemie - International Edition, 2003, v. 42, n. 13, p. 1491-1495 How to Cite? |
| Abstract | Mechanical displacement of the ring by around 40% along the approximately 9-nm long dumbbell-shaped component has been seen in a bistable redox-controllable [2]rotaxane. Chemical oxidation of the tetrathiafulvalene recognition station (green, see scheme) in the dumbbell-shaped component, which also contains a 1,5-dioxynaphthalene recognition station (red), results in the cyclobis(paraquat-p-phenylene) tetracation (blue) undergoing translation from the much preferred green station to the second-choice, red station. |
| Persistent Identifier | http://hdl.handle.net/10722/333592 |
| ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Tseng, Hsian Rong | - |
| dc.contributor.author | Vignon, Scott A. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.date.accessioned | 2023-10-06T05:20:51Z | - |
| dc.date.available | 2023-10-06T05:20:51Z | - |
| dc.date.issued | 2003 | - |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2003, v. 42, n. 13, p. 1491-1495 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/333592 | - |
| dc.description.abstract | Mechanical displacement of the ring by around 40% along the approximately 9-nm long dumbbell-shaped component has been seen in a bistable redox-controllable [2]rotaxane. Chemical oxidation of the tetrathiafulvalene recognition station (green, see scheme) in the dumbbell-shaped component, which also contains a 1,5-dioxynaphthalene recognition station (red), results in the cyclobis(paraquat-p-phenylene) tetracation (blue) undergoing translation from the much preferred green station to the second-choice, red station. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie - International Edition | - |
| dc.subject | Chemical switching | - |
| dc.subject | Molecular devices | - |
| dc.subject | Rotaxanes self-assembly | - |
| dc.subject | Supramolecular chemistry | - |
| dc.title | Toward chemically controlled nanoscale molecular machinery | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.200250453 | - |
| dc.identifier.scopus | eid_2-s2.0-0037418978 | - |
| dc.identifier.volume | 42 | - |
| dc.identifier.issue | 13 | - |
| dc.identifier.spage | 1491 | - |
| dc.identifier.epage | 1495 | - |
| dc.identifier.isi | WOS:000182337000008 | - |