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- Publisher Website: 10.1002/anie.199311821
- Scopus: eid_2-s2.0-33748216134
- WOS: WOS:A1993LU33800026
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Article: Dilithiation of Two Diphenyl Ethers Each Containing Two NHCH2 CH2 Y (Y = OMe, NMe2 ) Side Arms in ortho Positions: Assembly of “Adamantanoid” Li4 O2 N4 Cores
Title | Dilithiation of Two Diphenyl Ethers Each Containing Two NHCH<inf>2</inf>CH<inf>2</inf>Y (Y = OMe, NMe<inf>2</inf>) Side Arms in ortho Positions: Assembly of “Adamantanoid” Li<inf>4</inf>O<inf>2</inf>N<inf>4</inf> Cores |
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Authors | |
Issue Date | 1993 |
Citation | Angewandte Chemie International Edition in English, 1993, v. 32, n. 8, p. 1182-1184 How to Cite? |
Abstract | No N2Li2 units are formed on dilithiation of the RNH‐substituted ethers 1 and 2. Instead, the dimerization of two monomers leads to adamantanoid structures with Li4O2N4 frameworks and CH2CH2OMe and CH2CH2NMe2 side arms that are crucial for dimer formation. The adamantanoid structure of the Li2 compound prepared from 1 also persists in solution. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany |
Persistent Identifier | http://hdl.handle.net/10722/333599 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Cragg‐Hine, Ian | - |
dc.contributor.author | Davidson, Matthew G. | - |
dc.contributor.author | Kocian, Oldrich | - |
dc.contributor.author | Mair, Francis S. | - |
dc.contributor.author | Pohl, Ehmke | - |
dc.contributor.author | Raithby, Paul R. | - |
dc.contributor.author | Snaith, Ronald | - |
dc.contributor.author | Spencer, Neil | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.date.accessioned | 2023-10-06T05:20:55Z | - |
dc.date.available | 2023-10-06T05:20:55Z | - |
dc.date.issued | 1993 | - |
dc.identifier.citation | Angewandte Chemie International Edition in English, 1993, v. 32, n. 8, p. 1182-1184 | - |
dc.identifier.issn | 0570-0833 | - |
dc.identifier.uri | http://hdl.handle.net/10722/333599 | - |
dc.description.abstract | No N2Li2 units are formed on dilithiation of the RNH‐substituted ethers 1 and 2. Instead, the dimerization of two monomers leads to adamantanoid structures with Li4O2N4 frameworks and CH2CH2OMe and CH2CH2NMe2 side arms that are crucial for dimer formation. The adamantanoid structure of the Li2 compound prepared from 1 also persists in solution. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany | - |
dc.language | eng | - |
dc.relation.ispartof | Angewandte Chemie International Edition in English | - |
dc.title | Dilithiation of Two Diphenyl Ethers Each Containing Two NHCH<inf>2</inf>CH<inf>2</inf>Y (Y = OMe, NMe<inf>2</inf>) Side Arms in ortho Positions: Assembly of “Adamantanoid” Li<inf>4</inf>O<inf>2</inf>N<inf>4</inf> Cores | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/anie.199311821 | - |
dc.identifier.scopus | eid_2-s2.0-33748216134 | - |
dc.identifier.volume | 32 | - |
dc.identifier.issue | 8 | - |
dc.identifier.spage | 1182 | - |
dc.identifier.epage | 1184 | - |
dc.identifier.eissn | 1521-3773 | - |
dc.identifier.isi | WOS:A1993LU33800026 | - |