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- Publisher Website: 10.1002/anie.199014041
- Scopus: eid_2-s2.0-33751151679
- WOS: WOS:A1990EU00600011
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Article: A New Mode of Metal Encapsulation
| Title | A New Mode of Metal Encapsulation |
|---|---|
| Authors | |
| Issue Date | 1990 |
| Citation | Angewandte Chemie International Edition in English, 1990, v. 29, n. 12, p. 1404-1406 How to Cite? |
| Abstract | All ten oxygen atoms of the acyclic oligomer 1 c participate in the coordination of Ba2⊕ in the “scorpion” complex 1c · Ba(SCN)2 · Me2CO. The eleventh coordination site is occupied by the acetone molecule. A further characteristic of the complex are strong OHċN hydrogen bonds to the thiocyanate counterion. The ligands 1 also exhibit a high selectivity for cations with ionic radii of 1.2–1.3 Å, which could be explained with the help of molecular modeling studies. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany |
| Persistent Identifier | http://hdl.handle.net/10722/333704 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Bartlett, John S. | - |
| dc.contributor.author | Costello, James F. | - |
| dc.contributor.author | Mehani, Shrock | - |
| dc.contributor.author | Ramdas, S. | - |
| dc.contributor.author | Slawin, Alexandra M.Z. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.contributor.author | Williams, David J. | - |
| dc.date.accessioned | 2023-10-06T05:21:43Z | - |
| dc.date.available | 2023-10-06T05:21:43Z | - |
| dc.date.issued | 1990 | - |
| dc.identifier.citation | Angewandte Chemie International Edition in English, 1990, v. 29, n. 12, p. 1404-1406 | - |
| dc.identifier.issn | 0570-0833 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/333704 | - |
| dc.description.abstract | All ten oxygen atoms of the acyclic oligomer 1 c participate in the coordination of Ba2⊕ in the “scorpion” complex 1c · Ba(SCN)2 · Me2CO. The eleventh coordination site is occupied by the acetone molecule. A further characteristic of the complex are strong OHċN hydrogen bonds to the thiocyanate counterion. The ligands 1 also exhibit a high selectivity for cations with ionic radii of 1.2–1.3 Å, which could be explained with the help of molecular modeling studies. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie International Edition in English | - |
| dc.title | A New Mode of Metal Encapsulation | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.199014041 | - |
| dc.identifier.scopus | eid_2-s2.0-33751151679 | - |
| dc.identifier.volume | 29 | - |
| dc.identifier.issue | 12 | - |
| dc.identifier.spage | 1404 | - |
| dc.identifier.epage | 1406 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:A1990EU00600011 | - |