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- Publisher Website: 10.1055/s-2005-869963
- Scopus: eid_2-s2.0-23744500512
- WOS: WOS:000231083100025
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Article: Preparation of 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene from two versatile 1,3,5-tri(halosubstituted) 2,4,6-triethylbenzene derivatives
| Title | Preparation of 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene from two versatile 1,3,5-tri(halosubstituted) 2,4,6-triethylbenzene derivatives |
|---|---|
| Authors | |
| Keywords | Molecular receptors Pinwheel Staudinger reduction Substituted aromatic alkyl halides Triethylbenzene scaffold |
| Issue Date | 2005 |
| Citation | Synthesis, 2005, n. 12, p. 2080-2083 How to Cite? |
| Abstract | The use of 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene and the intermediates 1,3,5-tris(halomethyl)-2,4,6-triethylbenzene (halo = bromo and chloro) compounds, have been utilized as scaffolds for many molecular receptors. We report here for the first time a detailed practical synthetic procedure, starting from benzene, and in four straightforward steps, to prepare 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene, a very versatile molecular scaffold. The added advantage is the limited chromatography in the purification procedure. © Georg Thieme Verlag Stuttgart. |
| Persistent Identifier | http://hdl.handle.net/10722/341075 |
| ISSN | 2023 Impact Factor: 2.2 2023 SCImago Journal Rankings: 0.582 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Wallace, Karl J. | - |
| dc.contributor.author | Hanes, Robert | - |
| dc.contributor.author | Anslyn, Eric | - |
| dc.contributor.author | Morey, Jeroni | - |
| dc.contributor.author | Kilway, Kathleen V. | - |
| dc.contributor.author | Siegel, Jay | - |
| dc.date.accessioned | 2024-03-13T08:39:57Z | - |
| dc.date.available | 2024-03-13T08:39:57Z | - |
| dc.date.issued | 2005 | - |
| dc.identifier.citation | Synthesis, 2005, n. 12, p. 2080-2083 | - |
| dc.identifier.issn | 0039-7881 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/341075 | - |
| dc.description.abstract | The use of 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene and the intermediates 1,3,5-tris(halomethyl)-2,4,6-triethylbenzene (halo = bromo and chloro) compounds, have been utilized as scaffolds for many molecular receptors. We report here for the first time a detailed practical synthetic procedure, starting from benzene, and in four straightforward steps, to prepare 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene, a very versatile molecular scaffold. The added advantage is the limited chromatography in the purification procedure. © Georg Thieme Verlag Stuttgart. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Synthesis | - |
| dc.subject | Molecular receptors | - |
| dc.subject | Pinwheel | - |
| dc.subject | Staudinger reduction | - |
| dc.subject | Substituted aromatic alkyl halides | - |
| dc.subject | Triethylbenzene scaffold | - |
| dc.title | Preparation of 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene from two versatile 1,3,5-tri(halosubstituted) 2,4,6-triethylbenzene derivatives | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1055/s-2005-869963 | - |
| dc.identifier.scopus | eid_2-s2.0-23744500512 | - |
| dc.identifier.issue | 12 | - |
| dc.identifier.spage | 2080 | - |
| dc.identifier.epage | 2083 | - |
| dc.identifier.isi | WOS:000231083100025 | - |