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Article: Quadruple anionic buckybowls by solid-state chemistry of corannulene and cesium

TitleQuadruple anionic buckybowls by solid-state chemistry of corannulene and cesium
Authors
Issue Date2013
Citation
Journal of the American Chemical Society, 2013, v. 135, n. 34, p. 12857-12860 How to Cite?
AbstractThe buckybowl corannulene is known to be an excellent electron acceptor. UV photoelectron spectroscopy studies were performed with thin-film systems containing corannulene and cesium. Adsorption of submonolayer quantities of corannulene in ultrahigh vacuum onto thick Cs films, deposited at 100 K on a copper(111) substrate, induces a transfer of four electrons per molecule into the two lowest unoccupied orbitals. Annealing of thick corannulene layers on top of the cesium film leads to the formation of a stable film composed of C 20H104- ions coordinated to four Cs+ ions. First-principles calculations reveal, as the most stable configuration, four Cs+ ions sandwiched between two corannulene bowls. © 2013 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/341142
ISSN
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorBauert, Tobias-
dc.contributor.authorZoppi, Laura-
dc.contributor.authorKoller, Georg-
dc.contributor.authorSiegel, Jay S.-
dc.contributor.authorBaldridge, Kim K.-
dc.contributor.authorErnst, Karl Heinz-
dc.date.accessioned2024-03-13T08:40:29Z-
dc.date.available2024-03-13T08:40:29Z-
dc.date.issued2013-
dc.identifier.citationJournal of the American Chemical Society, 2013, v. 135, n. 34, p. 12857-12860-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/341142-
dc.description.abstractThe buckybowl corannulene is known to be an excellent electron acceptor. UV photoelectron spectroscopy studies were performed with thin-film systems containing corannulene and cesium. Adsorption of submonolayer quantities of corannulene in ultrahigh vacuum onto thick Cs films, deposited at 100 K on a copper(111) substrate, induces a transfer of four electrons per molecule into the two lowest unoccupied orbitals. Annealing of thick corannulene layers on top of the cesium film leads to the formation of a stable film composed of C 20H104- ions coordinated to four Cs+ ions. First-principles calculations reveal, as the most stable configuration, four Cs+ ions sandwiched between two corannulene bowls. © 2013 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleQuadruple anionic buckybowls by solid-state chemistry of corannulene and cesium-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja4063103-
dc.identifier.scopuseid_2-s2.0-84883291172-
dc.identifier.volume135-
dc.identifier.issue34-
dc.identifier.spage12857-
dc.identifier.epage12860-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000323876300058-

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