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- Publisher Website: 10.1055/s-0035-1562845
- Scopus: eid_2-s2.0-84981218350
- WOS: WOS:000383275700015
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Article: Synthesis of a Five-Fold-Differentiated 1,3,5,7,9-Pentasubstituted Corannulene: A Maximal Labeling Problem in the Context of Corannulene
Title | Synthesis of a Five-Fold-Differentiated 1,3,5,7,9-Pentasubstituted Corannulene: A Maximal Labeling Problem in the Context of Corannulene |
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Authors | |
Keywords | 1,3,5,7,9-pentasubstituted corannulene Diels-Alder cycloaddition reductive coupling |
Issue Date | 2016 |
Citation | Synlett, 2016, v. 27, n. 14, p. 2117-2122 How to Cite? |
Abstract | This work defines a maximally labeled isomer problem in the context of 1,3,5,7,9-pentasubstituted corannulenes and explores two new synthetic strategies for the construction of key C-C bonds in the corannulene nucleus: a) a Diels-Alder cycloaddition of thiophene dioxide and acenaphthene fragments; b) a manganese-mediated reductive coupling of benzylic halides, which tolerates carboxy ester functionality. It advances the area of curved aromatics based on corannulene by setting a new family of targets for chemical synthesis and providing additional general synthetic tools. |
Persistent Identifier | http://hdl.handle.net/10722/341190 |
ISSN | 2023 Impact Factor: 1.7 2023 SCImago Journal Rankings: 0.450 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Maag, Roman | - |
dc.contributor.author | Siegel, Jay S. | - |
dc.date.accessioned | 2024-03-13T08:40:53Z | - |
dc.date.available | 2024-03-13T08:40:53Z | - |
dc.date.issued | 2016 | - |
dc.identifier.citation | Synlett, 2016, v. 27, n. 14, p. 2117-2122 | - |
dc.identifier.issn | 0936-5214 | - |
dc.identifier.uri | http://hdl.handle.net/10722/341190 | - |
dc.description.abstract | This work defines a maximally labeled isomer problem in the context of 1,3,5,7,9-pentasubstituted corannulenes and explores two new synthetic strategies for the construction of key C-C bonds in the corannulene nucleus: a) a Diels-Alder cycloaddition of thiophene dioxide and acenaphthene fragments; b) a manganese-mediated reductive coupling of benzylic halides, which tolerates carboxy ester functionality. It advances the area of curved aromatics based on corannulene by setting a new family of targets for chemical synthesis and providing additional general synthetic tools. | - |
dc.language | eng | - |
dc.relation.ispartof | Synlett | - |
dc.subject | 1,3,5,7,9-pentasubstituted corannulene | - |
dc.subject | Diels-Alder cycloaddition | - |
dc.subject | reductive coupling | - |
dc.title | Synthesis of a Five-Fold-Differentiated 1,3,5,7,9-Pentasubstituted Corannulene: A Maximal Labeling Problem in the Context of Corannulene | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1055/s-0035-1562845 | - |
dc.identifier.scopus | eid_2-s2.0-84981218350 | - |
dc.identifier.volume | 27 | - |
dc.identifier.issue | 14 | - |
dc.identifier.spage | 2117 | - |
dc.identifier.epage | 2122 | - |
dc.identifier.eissn | 1437-2096 | - |
dc.identifier.isi | WOS:000383275700015 | - |