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Article: Partial bond localization in the crystal structure of trisbicyclo[2.2.1]heptabenzene and its effect on Cr-arene dynamics
Title | Partial bond localization in the crystal structure of trisbicyclo[2.2.1]heptabenzene and its effect on Cr-arene dynamics |
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Authors | |
Issue Date | 1995 |
Citation | Tetrahedron Letters, 1995, v. 36, n. 25, p. 4389-4392 How to Cite? |
Abstract | Trisbicyclo[2.2.1]heptabenzene 3 crystallizes in space group P21/c with cell dimensions a = 5.992 Å, b = 17.288 Å, c = 14.843 Å. Mild bond localization is seen in the benzene ring (dexo(ave) = 1.379Å; dendo(ave) = 1.417Å) and the annelation angle C(ar)C(ar)C(CH) is constricted to 106.5°. The structure supports a bicyclic strain effect on the bond localization in benzenoid aromatics. © 1995. |
Persistent Identifier | http://hdl.handle.net/10722/341454 |
ISSN | 2023 Impact Factor: 1.5 2023 SCImago Journal Rankings: 0.323 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Frank, Natia L. | - |
dc.contributor.author | Baldridge, Kim K. | - |
dc.contributor.author | Gantzel, Peter | - |
dc.contributor.author | Siegel, Jay S. | - |
dc.date.accessioned | 2024-03-13T08:42:56Z | - |
dc.date.available | 2024-03-13T08:42:56Z | - |
dc.date.issued | 1995 | - |
dc.identifier.citation | Tetrahedron Letters, 1995, v. 36, n. 25, p. 4389-4392 | - |
dc.identifier.issn | 0040-4039 | - |
dc.identifier.uri | http://hdl.handle.net/10722/341454 | - |
dc.description.abstract | Trisbicyclo[2.2.1]heptabenzene 3 crystallizes in space group P21/c with cell dimensions a = 5.992 Å, b = 17.288 Å, c = 14.843 Å. Mild bond localization is seen in the benzene ring (dexo(ave) = 1.379Å; dendo(ave) = 1.417Å) and the annelation angle C(ar)C(ar)C(CH) is constricted to 106.5°. The structure supports a bicyclic strain effect on the bond localization in benzenoid aromatics. © 1995. | - |
dc.language | eng | - |
dc.relation.ispartof | Tetrahedron Letters | - |
dc.title | Partial bond localization in the crystal structure of trisbicyclo[2.2.1]heptabenzene and its effect on Cr-arene dynamics | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/0040-4039(95)00857-9 | - |
dc.identifier.scopus | eid_2-s2.0-0029069567 | - |
dc.identifier.volume | 36 | - |
dc.identifier.issue | 25 | - |
dc.identifier.spage | 4389 | - |
dc.identifier.epage | 4392 | - |
dc.identifier.isi | WOS:A1995RE87600015 | - |