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Article: Trinuclear copper(I)-bipyridine triskelion: Template/bascule control of coordination complex stereochemistry in a trefoil knot precursor

TitleTrinuclear copper(I)-bipyridine triskelion: Template/bascule control of coordination complex stereochemistry in a trefoil knot precursor
Authors
KeywordsCoordination chemistry
Molecular design
Stereochemistry
Supramolecular chemistry
Issue Date2001
Citation
Angewandte Chemie - International Edition, 2001, v. 40, n. 4, p. 749-751 How to Cite?
AbstractThe construction of molecules such as knots and links can be facilitated by using metal-ligand coordination complexes as template structures; however, the control of the stereochemistry by cooperative steric interactions among metal-ligand sites remains a challenge. A simple, but general, cantilever control mechanism is demonstrated here through the stereoselective synthesis of a trinuclear copper(I)-bipyridine triskelion (see picture).
Persistent Identifierhttp://hdl.handle.net/10722/341513
ISSN
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWoods, Craig R.-
dc.contributor.authorBenaglia, Maurizio-
dc.contributor.authorToyota, Shinji-
dc.contributor.authorHardcastle, Kenneth-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:43:23Z-
dc.date.available2024-03-13T08:43:23Z-
dc.date.issued2001-
dc.identifier.citationAngewandte Chemie - International Edition, 2001, v. 40, n. 4, p. 749-751-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/341513-
dc.description.abstractThe construction of molecules such as knots and links can be facilitated by using metal-ligand coordination complexes as template structures; however, the control of the stereochemistry by cooperative steric interactions among metal-ligand sites remains a challenge. A simple, but general, cantilever control mechanism is demonstrated here through the stereoselective synthesis of a trinuclear copper(I)-bipyridine triskelion (see picture).-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectCoordination chemistry-
dc.subjectMolecular design-
dc.subjectStereochemistry-
dc.subjectSupramolecular chemistry-
dc.titleTrinuclear copper(I)-bipyridine triskelion: Template/bascule control of coordination complex stereochemistry in a trefoil knot precursor-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/1521-3773(20010216)40:4<749::AID-ANIE7490>3.0.CO;2-D-
dc.identifier.scopuseid_2-s2.0-0035804390-
dc.identifier.volume40-
dc.identifier.issue4-
dc.identifier.spage749-
dc.identifier.epage751-
dc.identifier.isiWOS:000167112700020-

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