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Article: Tetranuclear copper(I)-biphenanthroline gridwork: Violation of the principle of maximal donor coordination caused by intercalation and CH-to-N forces

TitleTetranuclear copper(I)-biphenanthroline gridwork: Violation of the principle of maximal donor coordination caused by intercalation and CH-to-N forces
Authors
KeywordsCoordination chemistry
Molecular design
Stereochemistry
Supramolecular chemistry
Issue Date2001
Citation
Angewandte Chemie - International Edition, 2001, v. 40, n. 4, p. 751-754 How to Cite?
AbstractDesign principles in polynuclear coordination complexes have been based on the idea that metal ions would acquire donor atoms up to the metal's ligand field preference, and donor ligands, such as 1,10-phenanthroline, would not leave donor atoms uncoordinated to a metal ion. The geometry of the simple molecular grid formed from a series of 3,3′-biphenanthrolines complexed with Cu1 or Ag1 ions set up a cleft that binds uncoordinated ligands through a combination of intercalation, solvation, and CH-to-N interactions (see picture).
Persistent Identifierhttp://hdl.handle.net/10722/341514
ISSN
2023 Impact Factor: 16.1
2023 SCImago Journal Rankings: 5.300
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorToyota, Shinji-
dc.contributor.authorWoods, Craig R.-
dc.contributor.authorBenaglia, Maurizio-
dc.contributor.authorHaldimann, Richard-
dc.contributor.authorWärnmark, Kenneth-
dc.contributor.authorHardcastle, Kenneth-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:43:23Z-
dc.date.available2024-03-13T08:43:23Z-
dc.date.issued2001-
dc.identifier.citationAngewandte Chemie - International Edition, 2001, v. 40, n. 4, p. 751-754-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/341514-
dc.description.abstractDesign principles in polynuclear coordination complexes have been based on the idea that metal ions would acquire donor atoms up to the metal's ligand field preference, and donor ligands, such as 1,10-phenanthroline, would not leave donor atoms uncoordinated to a metal ion. The geometry of the simple molecular grid formed from a series of 3,3′-biphenanthrolines complexed with Cu1 or Ag1 ions set up a cleft that binds uncoordinated ligands through a combination of intercalation, solvation, and CH-to-N interactions (see picture).-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectCoordination chemistry-
dc.subjectMolecular design-
dc.subjectStereochemistry-
dc.subjectSupramolecular chemistry-
dc.titleTetranuclear copper(I)-biphenanthroline gridwork: Violation of the principle of maximal donor coordination caused by intercalation and CH-to-N forces-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/1521-3773(20010216)40:4<751::AID-ANIE7510>3.0.CO;2-4-
dc.identifier.scopuseid_2-s2.0-0035804398-
dc.identifier.volume40-
dc.identifier.issue4-
dc.identifier.spage751-
dc.identifier.epage754-
dc.identifier.isiWOS:000167112700021-

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