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Article: A missing member of conjugated N-heterocycles: Realizing pyrido[1,2-α]azepine by reacting ruthenium alkenylcarbene complex with alkyne

TitleA missing member of conjugated N-heterocycles: Realizing pyrido[1,2-α]azepine by reacting ruthenium alkenylcarbene complex with alkyne
Authors
Zhou, XiaoxiHuang, FanpingTang, ChunZhuo, QingdeChen, ZhixinZhang, HongXia, Haiping
Issue Date2018
Citation
Chemical Communications, 2018, v. 54, n. 32, p. 4009-4012 How to Cite?
DOI: http://dx.doi.org/10.1039/c8cc00758f
AbstractDespite the excellent chemical properties of N-heterocycles, pyrido[1,2-α]azepine remains elusive due to its potential antiaromaticity and lability. Herein, we demonstrate the synthesis and characterization of the first bicyclic pyrido[1,2-α]azepine that leverages the coordination to the ruthenium center to promote the stability of N-bridged bicycle.
Persistent Identifierhttp://hdl.handle.net/10722/346666
ISSN
1359-7345
2023 Impact Factor: 4.3
2023 SCImago Journal Rankings: 1.133

 

DC FieldValueLanguage
dc.contributor.authorZhou, Xiaoxi-
dc.contributor.authorHuang, Fanping-
dc.contributor.authorTang, Chun-
dc.contributor.authorZhuo, Qingde-
dc.contributor.authorChen, Zhixin-
dc.contributor.authorZhang, Hong-
dc.contributor.authorXia, Haiping-
dc.date.accessioned2024-09-17T04:12:26Z-
dc.date.available2024-09-17T04:12:26Z-
dc.date.issued2018-
dc.identifier.citationChemical Communications, 2018, v. 54, n. 32, p. 4009-4012-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/346666-
dc.description.abstractDespite the excellent chemical properties of N-heterocycles, pyrido[1,2-α]azepine remains elusive due to its potential antiaromaticity and lability. Herein, we demonstrate the synthesis and characterization of the first bicyclic pyrido[1,2-α]azepine that leverages the coordination to the ruthenium center to promote the stability of N-bridged bicycle.-
dc.languageeng-
dc.relation.ispartofChemical Communications-
dc.titleA missing member of conjugated N-heterocycles: Realizing pyrido[1,2-α]azepine by reacting ruthenium alkenylcarbene complex with alkyne-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c8cc00758f-
dc.identifier.pmid29617019-
dc.identifier.scopuseid_2-s2.0-85045558033-
dc.identifier.volume54-
dc.identifier.issue32-
dc.identifier.spage4009-
dc.identifier.epage4012-
dc.identifier.eissn1364-548X-

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