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- Publisher Website: 10.1039/d0cc07423c
- Scopus: eid_2-s2.0-85101540284
- PMID: 33498077
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Article: Modulation of charge transport through single-molecule bilactam junctions by tuning hydrogen bonds
Title | Modulation of charge transport through single-molecule bilactam junctions by tuning hydrogen bonds |
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Authors | |
Issue Date | 2021 |
Citation | Chemical Communications, 2021, v. 57, n. 15, p. 1935-1938 How to Cite? |
Abstract | Bilactam derivatives with different side groups were synthesized and the twisting angle tuning effect induced by the intramolecular hydrogen bond on the charge transport through their single-molecule junctions was investigated. Molecules with strong intramolecular hydrogen bonds exhibited twice higher conductance because of the reduced dihedral twisting, which was reversible with the addition of hydrogen bond destroying solvent. Our findings reveal that the presence of intramolecular hydrogen bonds promotes the planarization of the molecular structure without additional transmission channels, offering a new strategy for controlling molecular switchesviatuning the molecular twisting. |
Persistent Identifier | http://hdl.handle.net/10722/346990 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 1.133 |
DC Field | Value | Language |
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dc.contributor.author | Chen, Yaorong | - |
dc.contributor.author | Wang, Hua Chun | - |
dc.contributor.author | Tang, Yongxiang | - |
dc.contributor.author | Zhou, Yu | - |
dc.contributor.author | Huang, Longfeng | - |
dc.contributor.author | Cao, Jian | - |
dc.contributor.author | Tang, Chun | - |
dc.contributor.author | Zhang, Manxi | - |
dc.contributor.author | Shi, Jia | - |
dc.contributor.author | Liu, Junyang | - |
dc.contributor.author | Ren, Xiancheng | - |
dc.contributor.author | Xu, Yun Xiang | - |
dc.contributor.author | Hong, Wenjing | - |
dc.date.accessioned | 2024-09-17T04:14:37Z | - |
dc.date.available | 2024-09-17T04:14:37Z | - |
dc.date.issued | 2021 | - |
dc.identifier.citation | Chemical Communications, 2021, v. 57, n. 15, p. 1935-1938 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/10722/346990 | - |
dc.description.abstract | Bilactam derivatives with different side groups were synthesized and the twisting angle tuning effect induced by the intramolecular hydrogen bond on the charge transport through their single-molecule junctions was investigated. Molecules with strong intramolecular hydrogen bonds exhibited twice higher conductance because of the reduced dihedral twisting, which was reversible with the addition of hydrogen bond destroying solvent. Our findings reveal that the presence of intramolecular hydrogen bonds promotes the planarization of the molecular structure without additional transmission channels, offering a new strategy for controlling molecular switchesviatuning the molecular twisting. | - |
dc.language | eng | - |
dc.relation.ispartof | Chemical Communications | - |
dc.title | Modulation of charge transport through single-molecule bilactam junctions by tuning hydrogen bonds | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/d0cc07423c | - |
dc.identifier.pmid | 33498077 | - |
dc.identifier.scopus | eid_2-s2.0-85101540284 | - |
dc.identifier.volume | 57 | - |
dc.identifier.issue | 15 | - |
dc.identifier.spage | 1935 | - |
dc.identifier.epage | 1938 | - |
dc.identifier.eissn | 1364-548X | - |