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Article: Generalized Domino-Driven Synthesis of Hollow Hybrid Carbon Spheres with Ultrafine Metal Nitrides/Oxides

TitleGeneralized Domino-Driven Synthesis of Hollow Hybrid Carbon Spheres with Ultrafine Metal Nitrides/Oxides
Authors
Keywordsdomino-driven synthesis
encapsulation
fast kinetics
hollow carbon spheres
hollow hybrid materials
interfacial copolymerization
MAP5: Improvement
metal nitrides/oxides
potassium-ion storage
ultrafine nanoparticles
Issue Date2020
Citation
Matter, 2020, v. 3, n. 1, p. 246-260 How to Cite?
AbstractWe have demonstrated an ingenious one-pot aqueous domino-driven synthesis toward hollow hybrid spheres with ultrafine metal nitrides/oxides in hollow carbon cavity. The micelle-interfacial copolymerization is applied for shell formation, while the copolymerization-generated H+ spontaneously triggers oxometallate condensation for encapsulation. By regulating the synthetic conditions, the encapsulated metal species can be well tailored with different sizes/contents (nanocluster to several nanometers) and compositions (VN, VO, MoN, WN, bimetal-based nitrides). The ultrafine VN confined in hollow carbon exhibits excellent potassium storage performance.
Persistent Identifierhttp://hdl.handle.net/10722/349436
ISSN
2023 Impact Factor: 17.3
2023 SCImago Journal Rankings: 5.048

 

DC FieldValueLanguage
dc.contributor.authorXu, Fei-
dc.contributor.authorDing, Baichuan-
dc.contributor.authorQiu, Yuqian-
dc.contributor.authorDong, Renhao-
dc.contributor.authorZhuang, Wanqi-
dc.contributor.authorXu, Xiaosa-
dc.contributor.authorHan, Haojie-
dc.contributor.authorYang, Jiaying-
dc.contributor.authorWei, Bingqing-
dc.contributor.authorWang, Hongqiang-
dc.contributor.authorKaskel, Stefan-
dc.date.accessioned2024-10-17T06:58:31Z-
dc.date.available2024-10-17T06:58:31Z-
dc.date.issued2020-
dc.identifier.citationMatter, 2020, v. 3, n. 1, p. 246-260-
dc.identifier.issn2590-2393-
dc.identifier.urihttp://hdl.handle.net/10722/349436-
dc.description.abstractWe have demonstrated an ingenious one-pot aqueous domino-driven synthesis toward hollow hybrid spheres with ultrafine metal nitrides/oxides in hollow carbon cavity. The micelle-interfacial copolymerization is applied for shell formation, while the copolymerization-generated H+ spontaneously triggers oxometallate condensation for encapsulation. By regulating the synthetic conditions, the encapsulated metal species can be well tailored with different sizes/contents (nanocluster to several nanometers) and compositions (VN, VO, MoN, WN, bimetal-based nitrides). The ultrafine VN confined in hollow carbon exhibits excellent potassium storage performance.-
dc.languageeng-
dc.relation.ispartofMatter-
dc.subjectdomino-driven synthesis-
dc.subjectencapsulation-
dc.subjectfast kinetics-
dc.subjecthollow carbon spheres-
dc.subjecthollow hybrid materials-
dc.subjectinterfacial copolymerization-
dc.subjectMAP5: Improvement-
dc.subjectmetal nitrides/oxides-
dc.subjectpotassium-ion storage-
dc.subjectultrafine nanoparticles-
dc.titleGeneralized Domino-Driven Synthesis of Hollow Hybrid Carbon Spheres with Ultrafine Metal Nitrides/Oxides-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.matt.2020.05.012-
dc.identifier.scopuseid_2-s2.0-85086672027-
dc.identifier.volume3-
dc.identifier.issue1-
dc.identifier.spage246-
dc.identifier.epage260-
dc.identifier.eissn2590-2385-

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