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- Publisher Website: 10.1016/j.matt.2020.05.012
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Article: Generalized Domino-Driven Synthesis of Hollow Hybrid Carbon Spheres with Ultrafine Metal Nitrides/Oxides
Title | Generalized Domino-Driven Synthesis of Hollow Hybrid Carbon Spheres with Ultrafine Metal Nitrides/Oxides |
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Authors | |
Keywords | domino-driven synthesis encapsulation fast kinetics hollow carbon spheres hollow hybrid materials interfacial copolymerization MAP5: Improvement metal nitrides/oxides potassium-ion storage ultrafine nanoparticles |
Issue Date | 2020 |
Citation | Matter, 2020, v. 3, n. 1, p. 246-260 How to Cite? |
Abstract | We have demonstrated an ingenious one-pot aqueous domino-driven synthesis toward hollow hybrid spheres with ultrafine metal nitrides/oxides in hollow carbon cavity. The micelle-interfacial copolymerization is applied for shell formation, while the copolymerization-generated H+ spontaneously triggers oxometallate condensation for encapsulation. By regulating the synthetic conditions, the encapsulated metal species can be well tailored with different sizes/contents (nanocluster to several nanometers) and compositions (VN, VO, MoN, WN, bimetal-based nitrides). The ultrafine VN confined in hollow carbon exhibits excellent potassium storage performance. |
Persistent Identifier | http://hdl.handle.net/10722/349436 |
ISSN | 2023 Impact Factor: 17.3 2023 SCImago Journal Rankings: 5.048 |
DC Field | Value | Language |
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dc.contributor.author | Xu, Fei | - |
dc.contributor.author | Ding, Baichuan | - |
dc.contributor.author | Qiu, Yuqian | - |
dc.contributor.author | Dong, Renhao | - |
dc.contributor.author | Zhuang, Wanqi | - |
dc.contributor.author | Xu, Xiaosa | - |
dc.contributor.author | Han, Haojie | - |
dc.contributor.author | Yang, Jiaying | - |
dc.contributor.author | Wei, Bingqing | - |
dc.contributor.author | Wang, Hongqiang | - |
dc.contributor.author | Kaskel, Stefan | - |
dc.date.accessioned | 2024-10-17T06:58:31Z | - |
dc.date.available | 2024-10-17T06:58:31Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Matter, 2020, v. 3, n. 1, p. 246-260 | - |
dc.identifier.issn | 2590-2393 | - |
dc.identifier.uri | http://hdl.handle.net/10722/349436 | - |
dc.description.abstract | We have demonstrated an ingenious one-pot aqueous domino-driven synthesis toward hollow hybrid spheres with ultrafine metal nitrides/oxides in hollow carbon cavity. The micelle-interfacial copolymerization is applied for shell formation, while the copolymerization-generated H+ spontaneously triggers oxometallate condensation for encapsulation. By regulating the synthetic conditions, the encapsulated metal species can be well tailored with different sizes/contents (nanocluster to several nanometers) and compositions (VN, VO, MoN, WN, bimetal-based nitrides). The ultrafine VN confined in hollow carbon exhibits excellent potassium storage performance. | - |
dc.language | eng | - |
dc.relation.ispartof | Matter | - |
dc.subject | domino-driven synthesis | - |
dc.subject | encapsulation | - |
dc.subject | fast kinetics | - |
dc.subject | hollow carbon spheres | - |
dc.subject | hollow hybrid materials | - |
dc.subject | interfacial copolymerization | - |
dc.subject | MAP5: Improvement | - |
dc.subject | metal nitrides/oxides | - |
dc.subject | potassium-ion storage | - |
dc.subject | ultrafine nanoparticles | - |
dc.title | Generalized Domino-Driven Synthesis of Hollow Hybrid Carbon Spheres with Ultrafine Metal Nitrides/Oxides | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/j.matt.2020.05.012 | - |
dc.identifier.scopus | eid_2-s2.0-85086672027 | - |
dc.identifier.volume | 3 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | 246 | - |
dc.identifier.epage | 260 | - |
dc.identifier.eissn | 2590-2385 | - |