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Article: Visible Light-Promoted Mono-Bromination of Aniline Derivatives and Nitrogen-Containing Heterocyclic Compounds via Electron Donor-Acceptor Complex

TitleVisible Light-Promoted Mono-Bromination of Aniline Derivatives and Nitrogen-Containing Heterocyclic Compounds via Electron Donor-Acceptor Complex
Authors
Keywordsaniline derivatives
EDA complex
mono-bromination
photocatalyst-free
photochemical reaction
Issue Date11-Jun-2024
PublisherWiley
Citation
Asian Journal of Organic Chemistry, 2024 How to Cite?
Abstract

We present a successful development of a photo-induced mono-bromination method for anilines, which eliminates the requirement for photocatalysts and excess bromine sources. Experimental investigations, complemented by computational analyses, establish that this method operates via the formation of an electron donor-acceptor (EDA) complex. This innovative approach enables the synthesis of highly regioselective mono-brominated products across a diverse range of substrates, all achieved under mild reaction conditions.


Persistent Identifierhttp://hdl.handle.net/10722/350695
ISSN
2023 Impact Factor: 2.8
2023 SCImago Journal Rankings: 0.578

 

DC FieldValueLanguage
dc.contributor.authorSun, Wenmo-
dc.contributor.authorYang, Wenjing-
dc.contributor.authorCheng, Hongying-
dc.contributor.authorZhou, Cong Ying-
dc.contributor.authorGuo, Zhen-
dc.date.accessioned2024-11-01T00:30:32Z-
dc.date.available2024-11-01T00:30:32Z-
dc.date.issued2024-06-11-
dc.identifier.citationAsian Journal of Organic Chemistry, 2024-
dc.identifier.issn2193-5807-
dc.identifier.urihttp://hdl.handle.net/10722/350695-
dc.description.abstract<p>We present a successful development of a photo-induced mono-bromination method for anilines, which eliminates the requirement for photocatalysts and excess bromine sources. Experimental investigations, complemented by computational analyses, establish that this method operates via the formation of an electron donor-acceptor (EDA) complex. This innovative approach enables the synthesis of highly regioselective mono-brominated products across a diverse range of substrates, all achieved under mild reaction conditions.</p>-
dc.languageeng-
dc.publisherWiley-
dc.relation.ispartofAsian Journal of Organic Chemistry-
dc.rightsThis work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.-
dc.subjectaniline derivatives-
dc.subjectEDA complex-
dc.subjectmono-bromination-
dc.subjectphotocatalyst-free-
dc.subjectphotochemical reaction-
dc.titleVisible Light-Promoted Mono-Bromination of Aniline Derivatives and Nitrogen-Containing Heterocyclic Compounds via Electron Donor-Acceptor Complex -
dc.typeArticle-
dc.identifier.doi10.1002/ajoc.202400180-
dc.identifier.scopuseid_2-s2.0-85199448920-
dc.identifier.eissn2193-5815-
dc.identifier.issnl2193-5807-

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