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Article: Fabrication of a solution-processed white light emitting diode containing a single dimeric copper(I) emitter featuring combined TADF and phosphorescence

TitleFabrication of a solution-processed white light emitting diode containing a single dimeric copper(I) emitter featuring combined TADF and phosphorescence
Authors
KeywordsCombined singlet and triplet harvesting
Combined thermally activated delayed fluorescence and phosphorescence
Dimeric copper(I) complexes
Organic light emitting diodes (OLEDs)
P∩N phosphine ligands
Thermally activated delayed fluorescence (TADF)
White emission
White light emitting OLED (WOLED)
Issue Date2021
Citation
Micromachines, 2021, v. 12, n. 12, article no. 1500 How to Cite?
AbstractLuminescent copper(I) complexes showing thermally activated delayed fluorescence (TADF) have developed to attractive emitter materials for organic light emitting diodes (OLEDs). Here, we study the brightly luminescent dimer Cu2Cl2(P∩N)2 (P∩N = diphenylphosphanyl-6-methyl-pyridine), which shows both TADF and phosphorescence at ambient temperature. A solution-processed OLED with a device structure ITO/PEDOT:PSS/PYD2: Cu2Cl2(P∩N)2/DPEPO (10 nm)/TPBi (40 nm)/LiF (1.2 nm)/Al (100 nm) shows warm white emission with moderate external quantum efficiency (EQE). Methods for EQE increase strategies are discussed.
Persistent Identifierhttp://hdl.handle.net/10722/352260

 

DC FieldValueLanguage
dc.contributor.authorCheng, Gang-
dc.contributor.authorZhou, Dongling-
dc.contributor.authorMonkowius, Uwe-
dc.contributor.authorYersin, Hartmut-
dc.date.accessioned2024-12-16T03:57:39Z-
dc.date.available2024-12-16T03:57:39Z-
dc.date.issued2021-
dc.identifier.citationMicromachines, 2021, v. 12, n. 12, article no. 1500-
dc.identifier.urihttp://hdl.handle.net/10722/352260-
dc.description.abstractLuminescent copper(I) complexes showing thermally activated delayed fluorescence (TADF) have developed to attractive emitter materials for organic light emitting diodes (OLEDs). Here, we study the brightly luminescent dimer Cu2Cl2(P∩N)2 (P∩N = diphenylphosphanyl-6-methyl-pyridine), which shows both TADF and phosphorescence at ambient temperature. A solution-processed OLED with a device structure ITO/PEDOT:PSS/PYD2: Cu2Cl2(P∩N)2/DPEPO (10 nm)/TPBi (40 nm)/LiF (1.2 nm)/Al (100 nm) shows warm white emission with moderate external quantum efficiency (EQE). Methods for EQE increase strategies are discussed.-
dc.languageeng-
dc.relation.ispartofMicromachines-
dc.subjectCombined singlet and triplet harvesting-
dc.subjectCombined thermally activated delayed fluorescence and phosphorescence-
dc.subjectDimeric copper(I) complexes-
dc.subjectOrganic light emitting diodes (OLEDs)-
dc.subjectP∩N phosphine ligands-
dc.subjectThermally activated delayed fluorescence (TADF)-
dc.subjectWhite emission-
dc.subjectWhite light emitting OLED (WOLED)-
dc.titleFabrication of a solution-processed white light emitting diode containing a single dimeric copper(I) emitter featuring combined TADF and phosphorescence-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.3390/mi12121500-
dc.identifier.scopuseid_2-s2.0-85120689310-
dc.identifier.volume12-
dc.identifier.issue12-
dc.identifier.spagearticle no. 1500-
dc.identifier.epagearticle no. 1500-
dc.identifier.eissn2072-666X-

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