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Article: [Cp*RuPb11]3−and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

Title[Cp*RuPb<inf>11</inf>]<sup>3−</sup>and [Cu@Cp*RuPb<inf>11</inf>]<sup>2−</sup>: centered and non-centered transition-metal substituted zintl icosahedra
Authors
Li, Ai MinWang, YiZavalij, Peter Y.Chen, FuMuñoz-Castro, AlvaroEichhorn, Bryan W.
Issue Date2020
Citation
Chemical Communications, 2020, v. 56, n. 74, p. 10859-10862 How to Cite?
DOI: http://dx.doi.org/10.1039/d0cc03656k
AbstractCluster anions [Cp*RuPb11]3−(1) and [Cu@Cp*RuPb11]2−(2) represent the first vertex-substituted zintl icosahedra and1is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes1and2are both 12-vertex, 26-electroncloso-clusters withC5vpoint symmetry and are static on the207Pb NMR time scale in solution.
Persistent Identifierhttp://hdl.handle.net/10722/355419
ISSN
1359-7345
2023 Impact Factor: 4.3
2023 SCImago Journal Rankings: 1.133

 

DC FieldValueLanguage
dc.contributor.authorLi, Ai Min-
dc.contributor.authorWang, Yi-
dc.contributor.authorZavalij, Peter Y.-
dc.contributor.authorChen, Fu-
dc.contributor.authorMuñoz-Castro, Alvaro-
dc.contributor.authorEichhorn, Bryan W.-
dc.date.accessioned2025-04-08T03:40:37Z-
dc.date.available2025-04-08T03:40:37Z-
dc.date.issued2020-
dc.identifier.citationChemical Communications, 2020, v. 56, n. 74, p. 10859-10862-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/355419-
dc.description.abstractCluster anions [Cp*RuPb11]3−(1) and [Cu@Cp*RuPb11]2−(2) represent the first vertex-substituted zintl icosahedra and1is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes1and2are both 12-vertex, 26-electroncloso-clusters withC5vpoint symmetry and are static on the207Pb NMR time scale in solution.-
dc.languageeng-
dc.relation.ispartofChemical Communications-
dc.title[Cp*RuPb<inf>11</inf>]<sup>3−</sup>and [Cu@Cp*RuPb<inf>11</inf>]<sup>2−</sup>: centered and non-centered transition-metal substituted zintl icosahedra-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/d0cc03656k-
dc.identifier.pmid32789413-
dc.identifier.scopuseid_2-s2.0-85091191717-
dc.identifier.volume56-
dc.identifier.issue74-
dc.identifier.spage10859-
dc.identifier.epage10862-
dc.identifier.eissn1364-548X-

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