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- Publisher Website: 10.1021/acs.inorgchem.1c01799
- Scopus: eid_2-s2.0-85116599915
- PMID: 34555280
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Article: Contrasting Bonding Extremes in Two [Ge6 ]n-Complexes: A Wadian Polyhedron (n = 2) versus a Hydrocarbon-like 2c-2e Polygermanide (n = 12)
| Title | Contrasting Bonding Extremes in Two [Ge<inf>6</inf>]<sup>n-</sup>Complexes: A Wadian Polyhedron (n = 2) versus a Hydrocarbon-like 2c-2e Polygermanide (n = 12) |
|---|---|
| Authors | |
| Issue Date | 2021 |
| Citation | Inorganic Chemistry, 2021, v. 60, n. 19, p. 14697-14705 How to Cite? |
| Abstract | [Nb(ν6-C6H3Me3)2] reacts with ethylenediamine (en) solutions of K4Ge9 in the presence of 18-crown-6 to give [(ν6-C6H3Me3)NbHGe6]2- (1) and [(ν6-C6H3Me3)NbGe6Nb(ν6-C6H3Me3)]2- (2) as their corresponding [K(18-crown-6)]+ salts. The crystalline solids are dark brown, air-sensitive, and sparingly soluble or insoluble in most solvents. The [K(18-crown-6)]+ salts of cluster ions 1 and 2 have been characterized by energy-dispersive X-ray (EDX) analysis, NMR studies, single-crystal X-ray diffraction, and electrospray ionization time-of-flight (ESI-TOF) mass spectrometry studies. Cluster ions 1 and 2 have markedly different [Ge6] moieties: an electron-deficient carborane-like subunit in 1 and a two-center, two-electron cyclohexane-like subunit in 2. |
| Persistent Identifier | http://hdl.handle.net/10722/355429 |
| ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Li, Ai Min | - |
| dc.contributor.author | Wang, Yi | - |
| dc.contributor.author | Zavalij, Peter Y. | - |
| dc.contributor.author | Chen, Yu Sheng | - |
| dc.contributor.author | Muñoz-Castro, Alvaro | - |
| dc.contributor.author | Eichhorn, Bryan W. | - |
| dc.date.accessioned | 2025-04-08T03:40:40Z | - |
| dc.date.available | 2025-04-08T03:40:40Z | - |
| dc.date.issued | 2021 | - |
| dc.identifier.citation | Inorganic Chemistry, 2021, v. 60, n. 19, p. 14697-14705 | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/355429 | - |
| dc.description.abstract | [Nb(ν6-C6H3Me3)2] reacts with ethylenediamine (en) solutions of K4Ge9 in the presence of 18-crown-6 to give [(ν6-C6H3Me3)NbHGe6]2- (1) and [(ν6-C6H3Me3)NbGe6Nb(ν6-C6H3Me3)]2- (2) as their corresponding [K(18-crown-6)]+ salts. The crystalline solids are dark brown, air-sensitive, and sparingly soluble or insoluble in most solvents. The [K(18-crown-6)]+ salts of cluster ions 1 and 2 have been characterized by energy-dispersive X-ray (EDX) analysis, NMR studies, single-crystal X-ray diffraction, and electrospray ionization time-of-flight (ESI-TOF) mass spectrometry studies. Cluster ions 1 and 2 have markedly different [Ge6] moieties: an electron-deficient carborane-like subunit in 1 and a two-center, two-electron cyclohexane-like subunit in 2. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Inorganic Chemistry | - |
| dc.title | Contrasting Bonding Extremes in Two [Ge<inf>6</inf>]<sup>n-</sup>Complexes: A Wadian Polyhedron (n = 2) versus a Hydrocarbon-like 2c-2e Polygermanide (n = 12) | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/acs.inorgchem.1c01799 | - |
| dc.identifier.pmid | 34555280 | - |
| dc.identifier.scopus | eid_2-s2.0-85116599915 | - |
| dc.identifier.volume | 60 | - |
| dc.identifier.issue | 19 | - |
| dc.identifier.spage | 14697 | - |
| dc.identifier.epage | 14705 | - |
| dc.identifier.eissn | 1520-510X | - |