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Article: Dynamic mechanostereochemical switching of a co-conformationally flexible [2]catenane controlled by specific ionic guests

TitleDynamic mechanostereochemical switching of a co-conformationally flexible [2]catenane controlled by specific ionic guests
Authors
Issue Date4-Mar-2024
PublisherNature Research
Citation
Nature Communications, 2024, v. 15, n. 1 How to Cite?
Abstract

Responsive synthetic receptors for adaptive recognition of different ionic guests in a competitive environment are valuable molecular tools for not only ion sensing and transport, but also the development of ion-responsive smart materials and related technologies. By virtue of the mechanical chelation and ability to undergo large-amplitude co-conformational changes, described herein is the discovery of a chameleon-like [2]catenane that selectively binds copper(I) or sulfate ions and its associated co-conformational mechanostereochemical switching. This work highlights not only the advantages and versatility of catenane as a molecular skeleton in receptor design, but also its potential in constructing complex responsive systems with multiple inputs and outputs.


Persistent Identifierhttp://hdl.handle.net/10722/357205
ISSN
2023 Impact Factor: 14.7
2023 SCImago Journal Rankings: 4.887
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYao, Yueliang-
dc.contributor.authorTse, Yuen Cheong-
dc.contributor.authorLai, Samuel Kin-Man-
dc.contributor.authorShi, Yixiang-
dc.contributor.authorLow, Kam-Hung-
dc.contributor.authorAu-Yeung, Ho Yu-
dc.date.accessioned2025-06-23T08:53:57Z-
dc.date.available2025-06-23T08:53:57Z-
dc.date.issued2024-03-04-
dc.identifier.citationNature Communications, 2024, v. 15, n. 1-
dc.identifier.issn2041-1723-
dc.identifier.urihttp://hdl.handle.net/10722/357205-
dc.description.abstract<p>Responsive synthetic receptors for adaptive recognition of different ionic guests in a competitive environment are valuable molecular tools for not only ion sensing and transport, but also the development of ion-responsive smart materials and related technologies. By virtue of the mechanical chelation and ability to undergo large-amplitude co-conformational changes, described herein is the discovery of a chameleon-like [2]catenane that selectively binds copper(I) or sulfate ions and its associated co-conformational mechanostereochemical switching. This work highlights not only the advantages and versatility of catenane as a molecular skeleton in receptor design, but also its potential in constructing complex responsive systems with multiple inputs and outputs.<br></p>-
dc.languageeng-
dc.publisherNature Research-
dc.relation.ispartofNature Communications-
dc.rightsThis work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.-
dc.titleDynamic mechanostereochemical switching of a co-conformationally flexible [2]catenane controlled by specific ionic guests-
dc.typeArticle-
dc.description.naturepublished_or_final_version-
dc.identifier.doi10.1038/s41467-024-46099-w-
dc.identifier.scopuseid_2-s2.0-85186567897-
dc.identifier.volume15-
dc.identifier.issue1-
dc.identifier.eissn2041-1723-
dc.identifier.isiWOS:001177070700001-
dc.identifier.issnl2041-1723-

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