A new binder-free and conductive-additive-free TiO2/WO3-W integrative anode material produced by laser ablation

Abstract

Although transition metal oxides anodes have attracted lots of attention, there are still many problems to be resolved. Complicated fabrication process, high cost and poor electrochemical performances are the most important ones, together hindering transition metal oxides anodes for practical use. Herein, we provide a new approach to fabricate a binder-free and conductive-additive-free TiO<inf>2</inf>/WO<inf>3</inf>-W integrative anode material through the nanosecond laser ablation and dip-coating technology, which simplifies the entire anode preparation process with no need for a conventional tape-casting procedure. Using this method, great time cost, machine cost and labor cost related to mixing and tape-casting process can be saved on the basis of good electrochemical performances. The prepared TiO<inf>2</inf>/WO<inf>3</inf>-W integrative anode realizes a first Coulombic efficiency of 75.6% and attains to a stable capacity within the first five cycles. It can still maintain a capacity of 600 mAh g⁻¹ in the range of 0.01–3 V vs. Li⁺/Li at a current rate of 0.2 C after 500 cycles. This work offers a new way to achieve a fast fabrication of the integrative anode for lithium ion battery, which is universal for other transition metals (such as Fe, Cu, Ni, Co, Mo, W etc.).