A novel method for solidification/stabilization of Cd(II), Hg(II), Cu(II), and Zn(II) by activated electrolytic manganese slag

Abstract

This study was aimed at removing and stabilizing heavy metals (Hg^II, Zn^II, Cu^II, and Cd^II). A novel material (named A-EMS) for heavy metal removal was proposed by ball grinding activated electrolytic manganese slag (EMS) with low content of sodium hydroxide. For different application scenarios, the two physical properties of the materials were developed: the powdery A-EMS (powder) was used to remove heavy metals from wastewater. In addition, the blocky A-EMS (porous brick) was used to build barrier walls for tailings ponds to prevent heavy metals from flowing out. The maximum removal amount of Hg(II) Cd(II), Zn(II), and Cu(II) by A-EMS were 475.35, 77.72, 259.70, and 203.20 mg/g in 30 min. The heavy metals ions were removed and fixed on A-EMS mainly through ion exchange and some forms of electrostatic adsorption and hydroxyl complexation. After consolidating the heavy metals, the compressive strength of the materials can reach 20 Mpa and the leaching toxicity met the national standard of China (GB/T 3838-2002) in 60 days. These excellent properties made A-EMS widely used to remove heavy metals in wastewater and to intercept and solidify heavy metals in mine wastewater.