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Article: The silver(I) complexes with non-planar di-2-pyrimidinyl sulfide induced by anion and solvent effect

TitleThe silver(I) complexes with non-planar di-2-pyrimidinyl sulfide induced by anion and solvent effect
Authors
Wan, Chong QingLi, Ai MinSun, Xin ZhanYan, Hao JieFeng, San YangWang, Zi JiaWang, Zhi Wei
KeywordsConfiguration
Non-planar
Solvent medium effect
Sulfide
Supramolecule
Issue Date1-Oct-2013
PublisherElsevier
Citation
Inorganica Chimica Acta, 2013, v. 407, p. 108-115 How to Cite?
DOI: http://dx.doi.org/10.1016/j.ica.2013.07.046
Abstract

The silver(I) complexes {[Ag(DprS)(CH3CN)](ClO 4)}∞ (1) with a ladder-like motif and [Ag 2(DprS)(CF3CO2)2]∞ (2) with a two-dimensional net were respectively obtained through solvent medium tuning effect (DprS = di-pyrimidinyl sulfide), while complex {[Ag 3(DprS)4(C2F5CO2)] (CF3SO3)2·H2O} ∞ (3) was achieved as a tape-like coordination motif in the presence of mixed counter anions. In 1-3, even in the crystalline state of the neat form DprS, each DprS molecule takes an unvaried non-planar configuration stabilized by intramolecular Npyrimidinyl⋯C pyrimidinyl contact. Complexes 1-3 and the DprS ligand were fully characterized through single-crystal X-ray diffraction, elemental analysis, FT-IR spectroscopy and luminescent emission measurement. The effect of the choice of solvent and anion on the structure is discussed. 


Persistent Identifierhttp://hdl.handle.net/10722/368153
ISSN
0020-1693
2023 Impact Factor: 2.7
2023 SCImago Journal Rankings: 0.386

 

DC FieldValueLanguage
dc.contributor.authorWan, Chong Qing-
dc.contributor.authorLi, Ai Min-
dc.contributor.authorSun, Xin Zhan-
dc.contributor.authorYan, Hao Jie-
dc.contributor.authorFeng, San Yang-
dc.contributor.authorWang, Zi Jia-
dc.contributor.authorWang, Zhi Wei-
dc.date.accessioned2025-12-24T00:36:32Z-
dc.date.available2025-12-24T00:36:32Z-
dc.date.issued2013-10-01-
dc.identifier.citationInorganica Chimica Acta, 2013, v. 407, p. 108-115-
dc.identifier.issn0020-1693-
dc.identifier.urihttp://hdl.handle.net/10722/368153-
dc.description.abstract<p>The silver(I) complexes {[Ag(DprS)(CH3CN)](ClO 4)}∞ (1) with a ladder-like motif and [Ag 2(DprS)(CF3CO2)2]∞ (2) with a two-dimensional net were respectively obtained through solvent medium tuning effect (DprS = di-pyrimidinyl sulfide), while complex {[Ag 3(DprS)4(C2F5CO2)] (CF3SO3)2·H2O} ∞ (3) was achieved as a tape-like coordination motif in the presence of mixed counter anions. In 1-3, even in the crystalline state of the neat form DprS, each DprS molecule takes an unvaried non-planar configuration stabilized by intramolecular Npyrimidinyl⋯C pyrimidinyl contact. Complexes 1-3 and the DprS ligand were fully characterized through single-crystal X-ray diffraction, elemental analysis, FT-IR spectroscopy and luminescent emission measurement. The effect of the choice of solvent and anion on the structure is discussed. </p>-
dc.languageeng-
dc.publisherElsevier-
dc.relation.ispartofInorganica Chimica Acta-
dc.rightsThis work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.-
dc.subjectConfiguration-
dc.subjectNon-planar-
dc.subjectSolvent medium effect-
dc.subjectSulfide-
dc.subjectSupramolecule-
dc.titleThe silver(I) complexes with non-planar di-2-pyrimidinyl sulfide induced by anion and solvent effect -
dc.typeArticle-
dc.identifier.doi10.1016/j.ica.2013.07.046-
dc.identifier.scopuseid_2-s2.0-84884505711-
dc.identifier.volume407-
dc.identifier.spage108-
dc.identifier.epage115-
dc.identifier.eissn1873-3255-
dc.identifier.issnl0020-1693-

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