Mutual-benefit modification of the coagulant solution and fly ash for enhanced sludge dewatering

Abstract

Faced with the escalating volume of municipal sludge from wastewater treatment plants, urgent measures are required to enhance the sludge dewatering efficiency. This study introduces an innovative and cost-effective approach for mutual modifications of AlCl3 coagulant solution (AC) and fly ash (FA) powder as additives to significantly enhance sludge dewaterability. Unlike the traditional method that modifies agents alone, our technique achieves dual functionalities via blending FA with AC at room temperature. The modified FA (MFA) exhibits a 60 % increase in specific surface area to 2.176 m2/g and ζ-potential shift from –22.2 to +2.0 mV, meanwhile enhances the metal ions content in the modified AC (MAC) by dissolving 96.5 % of Ca, 70.3 % of Mg, 10.6 % of Fe, and 6.1 % of Al ions from FA. When sludge is treated with 5 % MAC and 10 % MFA, the water content in the filter cake is reduced from 84.9 % originally to 52.9 % through plate-frame pressure filtration (PFPF), a significant improvement over 65.4 % for that with unmodified AC and FA treatment, corresponding to the decreased specific resistance to filtration (SRF) and increased the filtration flux during the draining phase. The notable dewaterability enhancement through AC and FA modification is due to the enhanced flocculation and charge neutralization by the abundant metal ions in MAC, coupled with the MFA-facilitated water adsorption and drainage channel maintenance. This one-step, double-benefit modification not only surpasses traditional methods in dewatering efficiency but also reduces sludge treatment costs by 42.4 %, offering a sustainable solution to the increasing challenges of municipal sludge management.