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Article: Reaction of a (Salen)ruthenium(VI) nitrido complex with isocyanide

TitleReaction of a (Salen)ruthenium(VI) nitrido complex with isocyanide
Authors
Kwong, HKMan, WLXiang, JWong, WTLau, TC
Issue Date2009
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2009, v. 48 n. 7, p. 3080-3086 How to Cite?
DOI: http://dx.doi.org/10.1021/ic802338f
AbstractThe treatment of [Ru VI(N)(L)(MeOH)]PF 6 (1) (L=N,N′-bis(salicylidene)-o-cyclohexyldiamine dianion) with 2 equiv of RNC (R ) (a) tBu, (b) Cy) in CH 2Cl 2 affords a mixture of blue cis-β-[Ru III(NCNR)(L)(CNR)] (2) and green trans-[Ru III(L)(CNR) 2]PF 6 (3) products. The reduction of 3 with a stoichiometric amount of Cp 2Co in CH 3CN gives red trans-[RuII(L)(CNR) 2] (4). Refluxing 4 with 3 equiv of RNC in methanol in the presence of 5 equiv of NH 4PF 6 affords a yellow complex, mer-[RuII(η 3-HL)(CNR) 3](PF 6) (5), in which the ligand is in an η 3-coordination mode. These complexes are characterized by IR, UV-vis, ESI-MS, CV, magnetic measurements, and CHN elemental analysis. The structures of 2a, 3a, 4a, 4b, and 5a have been determined by X-ray crystallography. © 2009 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/58329
ISSN
0020-1669
2021 Impact Factor: 5.436
2020 SCImago Journal Rankings: 1.348
ISI Accession Number ID
WOS:000264759500045
Funding AgencyGrant Number
Research Grants Council of Hong KongCityU 101505
CityU 2/06C
Funding Information:

The work described in this paper was supported by the Research Grants Council of Hong Kong (CityU 101505, CityU 2/06C).

References
References in Scopus
Grants
Green Oxidation Chemistry and Technology

 

DC FieldValueLanguage
dc.contributor.authorKwong, HKen_HK
dc.contributor.authorMan, WLen_HK
dc.contributor.authorXiang, Jen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorLau, TCen_HK
dc.date.accessioned2010-05-31T03:28:24Z-
dc.date.available2010-05-31T03:28:24Z-
dc.date.issued2009en_HK
dc.identifier.citationInorganic Chemistry, 2009, v. 48 n. 7, p. 3080-3086en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/58329-
dc.description.abstractThe treatment of [Ru VI(N)(L)(MeOH)]PF 6 (1) (L=N,N′-bis(salicylidene)-o-cyclohexyldiamine dianion) with 2 equiv of RNC (R ) (a) tBu, (b) Cy) in CH 2Cl 2 affords a mixture of blue cis-β-[Ru III(NCNR)(L)(CNR)] (2) and green trans-[Ru III(L)(CNR) 2]PF 6 (3) products. The reduction of 3 with a stoichiometric amount of Cp 2Co in CH 3CN gives red trans-[RuII(L)(CNR) 2] (4). Refluxing 4 with 3 equiv of RNC in methanol in the presence of 5 equiv of NH 4PF 6 affords a yellow complex, mer-[RuII(η 3-HL)(CNR) 3](PF 6) (5), in which the ligand is in an η 3-coordination mode. These complexes are characterized by IR, UV-vis, ESI-MS, CV, magnetic measurements, and CHN elemental analysis. The structures of 2a, 3a, 4a, 4b, and 5a have been determined by X-ray crystallography. © 2009 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleReaction of a (Salen)ruthenium(VI) nitrido complex with isocyanideen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=48&spage=3080&epage=3086&date=2009&atitle=Reaction+of+a+(Salen)Ruthenium(VI)+Nitrido+Complex+with+Isocyanide+en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic802338fen_HK
dc.identifier.scopuseid_2-s2.0-64349085823en_HK
dc.identifier.hkuros156613en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-64349085823&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume48en_HK
dc.identifier.issue7en_HK
dc.identifier.spage3080en_HK
dc.identifier.epage3086en_HK
dc.identifier.isiWOS:000264759500045-
dc.publisher.placeUnited Statesen_HK
dc.relation.projectGreen Oxidation Chemistry and Technology-
dc.identifier.scopusauthoridKwong, HK=7003727185en_HK
dc.identifier.scopusauthoridMan, WL=7005307944en_HK
dc.identifier.scopusauthoridXiang, J=36467466600en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridLau, TC=7102222310en_HK
dc.identifier.issnl0020-1669-

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