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Article: Synthesis, structure, and ion-binding properties of luminescent gold(I) alkynylcalix[4]crown-5 complexes

TitleSynthesis, structure, and ion-binding properties of luminescent gold(I) alkynylcalix[4]crown-5 complexes
Authors
Yam, VWWYip, SKYuan, LHCheung, KLZhu, NCheung, KK
Issue Date2003
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 2003, v. 22 n. 13, p. 2630-2637 How to Cite?
DOI: http://dx.doi.org/10.1021/om030021c
AbstractA series of luminescent dinuclear gold(I) alkynylcalix[4]crown-5 complexes, [(R nR′ 3-nP)Au] 2L (n = 0-3) (R = Ph, R′ = o-Tol, p-Tol) H 2L = 5,17-diethynyl-25,27-dimethoxycalix[4]arene-crown-5, have been synthesized and structurally characterized. The binding properties of the complexes toward alkali metal ions (K + and Na +) have been studied by UV - visible spectrophotometry. The dinuclear gold(I) alkynylcalix[4]crown-5 complexes were shown to exhibit preferential binding toward K + over Na + ions.
Persistent Identifierhttp://hdl.handle.net/10722/68930
ISSN
0276-7333
2023 Impact Factor: 2.5
2023 SCImago Journal Rankings: 0.654
ISI Accession Number ID
WOS:000183513700014
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorYip, SKen_HK
dc.contributor.authorYuan, LHen_HK
dc.contributor.authorCheung, KLen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorCheung, KKen_HK
dc.date.accessioned2010-09-06T06:09:00Z-
dc.date.available2010-09-06T06:09:00Z-
dc.date.issued2003en_HK
dc.identifier.citationOrganometallics, 2003, v. 22 n. 13, p. 2630-2637en_HK
dc.identifier.issn0276-7333en_HK
dc.identifier.urihttp://hdl.handle.net/10722/68930-
dc.description.abstractA series of luminescent dinuclear gold(I) alkynylcalix[4]crown-5 complexes, [(R nR′ 3-nP)Au] 2L (n = 0-3) (R = Ph, R′ = o-Tol, p-Tol) H 2L = 5,17-diethynyl-25,27-dimethoxycalix[4]arene-crown-5, have been synthesized and structurally characterized. The binding properties of the complexes toward alkali metal ions (K + and Na +) have been studied by UV - visible spectrophotometry. The dinuclear gold(I) alkynylcalix[4]crown-5 complexes were shown to exhibit preferential binding toward K + over Na + ions.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_HK
dc.relation.ispartofOrganometallicsen_HK
dc.titleSynthesis, structure, and ion-binding properties of luminescent gold(I) alkynylcalix[4]crown-5 complexesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0276-7333&volume=22&spage=2630&epage=2637&date=2003&atitle=Synthesis,+Structure,+and+Ion-Binding+Properties+of+Luminescent+Gold(I)+Alkynylcalix[4]+Crown-5+Complexes++en_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/om030021cen_HK
dc.identifier.scopuseid_2-s2.0-0037524238en_HK
dc.identifier.hkuros91191en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037524238&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume22en_HK
dc.identifier.issue13en_HK
dc.identifier.spage2630en_HK
dc.identifier.epage2637en_HK
dc.identifier.isiWOS:000183513700014-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridYip, SK=7102133674en_HK
dc.identifier.scopusauthoridYuan, LH=55236100100en_HK
dc.identifier.scopusauthoridCheung, KL=7402406646en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridCheung, KK=7402406613en_HK
dc.identifier.issnl0276-7333-

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