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- Publisher Website: 10.1002/asia.200600067
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- PMID: 17441063
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Article: Luminescent molecular copper(I) alkynyl open cubes: Synthesis, structural characterization, electronic structure, photophysics, and photochemistry
Title | Luminescent molecular copper(I) alkynyl open cubes: Synthesis, structural characterization, electronic structure, photophysics, and photochemistry |
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Authors | |
Keywords | Alkyne ligands Copper Density functional calculations Luminescence Photochemistry |
Issue Date | 2006 |
Publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www.wiley-vch.de/publish/en/journals/alphabeticIndex/2451 |
Citation | Chemistry - An Asian Journal, 2006, v. 1 n. 1-2, p. 273-286 How to Cite? |
Abstract | A novel class of tetranuclear copper(I) alkynyl complexes with an "open-cube" structure was synthesized. The crystal structure of [Cu4{P(p-MeC6H4)3} 4(μ3-η1,η1, η2-C ≡ C-p-MeO-C6H4) 3]PF6 was determined. These complexes were found to display dual emission behavior. Through systematic comparison studies on the electronic absorption and photoluminescence properties of a series of [Cu 4(PR3)4(μ3-η1, η1,η2-C ≡ CR′)3] + complexes, together with density functional theory (DFT) calculations at the PBE1PBE level on the model complex [Cu4(PH 3)4-(μ3-η1,η1, η2-C ≡ C-p-MeOC6H4)3] +, the nature of their emission origins was probed. Their photochemical properties were also investigated by oxidative quenching experiments and transient absorption spectroscopy. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA. |
Persistent Identifier | http://hdl.handle.net/10722/68980 |
ISSN | 2023 Impact Factor: 3.5 2023 SCImago Journal Rankings: 0.846 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chan, CL | en_HK |
dc.contributor.author | Cheung, KL | en_HK |
dc.contributor.author | Lam, WH | en_HK |
dc.contributor.author | Cheng, ECC | en_HK |
dc.contributor.author | Zhu, N | en_HK |
dc.contributor.author | Choi, SWK | en_HK |
dc.contributor.author | Yam, VWW | en_HK |
dc.date.accessioned | 2010-09-06T06:09:28Z | - |
dc.date.available | 2010-09-06T06:09:28Z | - |
dc.date.issued | 2006 | en_HK |
dc.identifier.citation | Chemistry - An Asian Journal, 2006, v. 1 n. 1-2, p. 273-286 | en_HK |
dc.identifier.issn | 1861-4728 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/68980 | - |
dc.description.abstract | A novel class of tetranuclear copper(I) alkynyl complexes with an "open-cube" structure was synthesized. The crystal structure of [Cu4{P(p-MeC6H4)3} 4(μ3-η1,η1, η2-C ≡ C-p-MeO-C6H4) 3]PF6 was determined. These complexes were found to display dual emission behavior. Through systematic comparison studies on the electronic absorption and photoluminescence properties of a series of [Cu 4(PR3)4(μ3-η1, η1,η2-C ≡ CR′)3] + complexes, together with density functional theory (DFT) calculations at the PBE1PBE level on the model complex [Cu4(PH 3)4-(μ3-η1,η1, η2-C ≡ C-p-MeOC6H4)3] +, the nature of their emission origins was probed. Their photochemical properties were also investigated by oxidative quenching experiments and transient absorption spectroscopy. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www.wiley-vch.de/publish/en/journals/alphabeticIndex/2451 | en_HK |
dc.relation.ispartof | Chemistry - An Asian Journal | en_HK |
dc.subject | Alkyne ligands | en_HK |
dc.subject | Copper | en_HK |
dc.subject | Density functional calculations | en_HK |
dc.subject | Luminescence | en_HK |
dc.subject | Photochemistry | en_HK |
dc.title | Luminescent molecular copper(I) alkynyl open cubes: Synthesis, structural characterization, electronic structure, photophysics, and photochemistry | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1861-4728&volume=1&issue=1-2&spage=273&epage=286&date=2006&atitle=Luminescent+molecular+copper(I)+alkynyl+open+cubes:+synthesis,+structural+characterization,+electronic+structure,+photophysics,+and+photochemistry | en_HK |
dc.identifier.email | Lam, WH: chsue@hku.hk | en_HK |
dc.identifier.email | Zhu, N: nzhu@hkucc.hku.hk | en_HK |
dc.identifier.email | Yam, VWW: wwyam@hku.hk | en_HK |
dc.identifier.authority | Lam, WH=rp00719 | en_HK |
dc.identifier.authority | Zhu, N=rp00845 | en_HK |
dc.identifier.authority | Yam, VWW=rp00822 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/asia.200600067 | en_HK |
dc.identifier.pmid | 17441063 | - |
dc.identifier.scopus | eid_2-s2.0-33748648373 | en_HK |
dc.identifier.hkuros | 125278 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33748648373&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 1 | en_HK |
dc.identifier.issue | 1-2 | en_HK |
dc.identifier.spage | 273 | en_HK |
dc.identifier.epage | 286 | en_HK |
dc.identifier.isi | WOS:000243157500031 | - |
dc.publisher.place | Germany | en_HK |
dc.identifier.scopusauthorid | Chan, CL=7404813631 | en_HK |
dc.identifier.scopusauthorid | Cheung, KL=7402406646 | en_HK |
dc.identifier.scopusauthorid | Lam, WH=26642862800 | en_HK |
dc.identifier.scopusauthorid | Cheng, ECC=7201743424 | en_HK |
dc.identifier.scopusauthorid | Zhu, N=7201449530 | en_HK |
dc.identifier.scopusauthorid | Choi, SWK=14526815000 | en_HK |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_HK |
dc.identifier.issnl | 1861-471X | - |