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- Publisher Website: 10.1021/ol000107r
- Scopus: eid_2-s2.0-0034720956
- PMID: 10930251
- WOS: WOS:000088346400014
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Article: Amidation of saturated C-H bonds catalyzed by electron-deficient ruthenium and manganese porphyrins. A highly catalytic nitrogen atom transfer process
Title | Amidation of saturated C-H bonds catalyzed by electron-deficient ruthenium and manganese porphyrins. A highly catalytic nitrogen atom transfer process |
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Authors | |
Issue Date | 2000 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html |
Citation | Organic Letters, 2000, v. 2 n. 15, p. 2233-2236 How to Cite? |
Abstract | (equation presented) Amidation of a variety of hydrocarbons with PhI=NTs catalyzed by ruthenium and manganese meso-tetrakis(pentafluorophenyl)porphyrins 1 and 2 afforded N-substituted amides in up to 92% yields with good to excellent substrate conversions. By employing catalyst 2, exceptionally high turnovers (up to 2600) were achieved, and the amidations can be effected by directly using PhI(OAc)2/NH2R as amidating reagents; in the case of R = COCF3 a direct amination was realized in up to 90% yield. |
Persistent Identifier | http://hdl.handle.net/10722/69077 |
ISSN | 2023 Impact Factor: 4.9 2023 SCImago Journal Rankings: 1.245 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Yu, XQ | en_HK |
dc.contributor.author | Huang, JS | en_HK |
dc.contributor.author | Zhou, XG | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.date.accessioned | 2010-09-06T06:10:21Z | - |
dc.date.available | 2010-09-06T06:10:21Z | - |
dc.date.issued | 2000 | en_HK |
dc.identifier.citation | Organic Letters, 2000, v. 2 n. 15, p. 2233-2236 | en_HK |
dc.identifier.issn | 1523-7060 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69077 | - |
dc.description.abstract | (equation presented) Amidation of a variety of hydrocarbons with PhI=NTs catalyzed by ruthenium and manganese meso-tetrakis(pentafluorophenyl)porphyrins 1 and 2 afforded N-substituted amides in up to 92% yields with good to excellent substrate conversions. By employing catalyst 2, exceptionally high turnovers (up to 2600) were achieved, and the amidations can be effected by directly using PhI(OAc)2/NH2R as amidating reagents; in the case of R = COCF3 a direct amination was realized in up to 90% yield. | en_HK |
dc.language | eng | en_HK |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html | en_HK |
dc.relation.ispartof | Organic Letters | en_HK |
dc.title | Amidation of saturated C-H bonds catalyzed by electron-deficient ruthenium and manganese porphyrins. A highly catalytic nitrogen atom transfer process | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1523-7060&volume=2&issue=15&spage=2233&epage=2236&date=2000&atitle=Amidation+of+saturated+C-H+bonds+catalyzed+by+electron-deficient+ruthenium+and+manganese+porphyrins.++A+highly+catalytic+nitrogen+atom+transfer+process | en_HK |
dc.identifier.email | Huang, JS:jshuang@hkucc.hku.hk | en_HK |
dc.identifier.email | Che, CM:cmche@hku.hk | en_HK |
dc.identifier.authority | Huang, JS=rp00709 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/ol000107r | - |
dc.identifier.pmid | 10930251 | en_HK |
dc.identifier.scopus | eid_2-s2.0-0034720956 | en_HK |
dc.identifier.hkuros | 64755 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0034720956&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 2 | en_HK |
dc.identifier.issue | 15 | en_HK |
dc.identifier.spage | 2233 | en_HK |
dc.identifier.epage | 2236 | en_HK |
dc.identifier.isi | WOS:000088346400014 | - |
dc.publisher.place | United States | en_HK |
dc.identifier.scopusauthorid | Yu, XQ=37861478700 | en_HK |
dc.identifier.scopusauthorid | Huang, JS=7407192639 | en_HK |
dc.identifier.scopusauthorid | Zhou, XG=37105544400 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.issnl | 1523-7052 | - |