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Article: Direct Radical Polymerization of 4-Styryldiphenylphosphine: Preparation of Cross-Linked and Non-Cross-Linked Triphenylphosphine-Containing Polystyrene Polymers

TitleDirect Radical Polymerization of 4-Styryldiphenylphosphine: Preparation of Cross-Linked and Non-Cross-Linked Triphenylphosphine-Containing Polystyrene Polymers
Authors
Choi, MKWHe, HSToy, PH
Issue Date2003
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/joc
Citation
Journal Of Organic Chemistry, 2003, v. 68 n. 25, p. 9831-9834 How to Cite?
DOI: http://dx.doi.org/10.1021/jo035226+
AbstractWe report herein a simple synthesis of 4-styryldiphenylphosphine and the radical copolymerization of it with styrene, both with and without a cross-linker, to directly form cross-linked and non-cross-linked polystyrene supported triphenylphosphine in which the level of phosphine incorporation can be easily and accurately controlled. The utility of these polymers is demonstrated by their use in Mitsunobu and alcohol bromination reactions.
Persistent Identifierhttp://hdl.handle.net/10722/69164
ISSN
0022-3263
2023 Impact Factor: 3.3
2023 SCImago Journal Rankings: 0.724
ISI Accession Number ID
WOS:000187016700042
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorChoi, MKWen_HK
dc.contributor.authorHe, HSen_HK
dc.contributor.authorToy, PHen_HK
dc.date.accessioned2010-09-06T06:11:09Z-
dc.date.available2010-09-06T06:11:09Z-
dc.date.issued2003en_HK
dc.identifier.citationJournal Of Organic Chemistry, 2003, v. 68 n. 25, p. 9831-9834en_HK
dc.identifier.issn0022-3263en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69164-
dc.description.abstractWe report herein a simple synthesis of 4-styryldiphenylphosphine and the radical copolymerization of it with styrene, both with and without a cross-linker, to directly form cross-linked and non-cross-linked polystyrene supported triphenylphosphine in which the level of phosphine incorporation can be easily and accurately controlled. The utility of these polymers is demonstrated by their use in Mitsunobu and alcohol bromination reactions.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jocen_HK
dc.relation.ispartofJournal of Organic Chemistryen_HK
dc.titleDirect Radical Polymerization of 4-Styryldiphenylphosphine: Preparation of Cross-Linked and Non-Cross-Linked Triphenylphosphine-Containing Polystyrene Polymersen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-3263&volume=68&spage=9831&epage=9834&date=2003&atitle=Direct+radical+polymerization+of+4-styryldiphenylphosphine:+preparation+of+cross-linked+and+non-cross-linked+triphenylphosphine-containing+polystyrene+polymers+en_HK
dc.identifier.emailToy, PH:phtoy@hkucc.hku.hken_HK
dc.identifier.authorityToy, PH=rp00791en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jo035226+en_HK
dc.identifier.scopuseid_2-s2.0-0344235343en_HK
dc.identifier.hkuros90439en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0344235343&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume68en_HK
dc.identifier.issue25en_HK
dc.identifier.spage9831en_HK
dc.identifier.epage9834en_HK
dc.identifier.isiWOS:000187016700042-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridChoi, MKW=7402093591en_HK
dc.identifier.scopusauthoridHe, HS=7402292173en_HK
dc.identifier.scopusauthoridToy, PH=7006579247en_HK
dc.identifier.issnl0022-3263-

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