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Article: Conjugated copolymers containing low bandgap rhenium(I) complexes
| Title | Conjugated copolymers containing low bandgap rhenium(I) complexes | ||||||
|---|---|---|---|---|---|---|---|
| Authors | |||||||
| Keywords | Conjugated polymer Low bandgap Metal-containing polymer Morphology Photovoltaic Rhenium(I) | ||||||
| Issue Date | 2010 | ||||||
| Publisher | Wiley - V C H Verlag GmbH & Co KGaA. | ||||||
| Citation | Macromolecular Rapid Communications, 2010, v. 31 n. 9-10, p. 875-882 How to Cite? | ||||||
| Abstract | Conjugated copolymers with novel low bandgap rhenium(I) complexes on the polymer mainchain are reported. The low bandgap metal-containing polymers were synthesized by Suzuki cross-coupling polycondensation or Stille coupling polymerization. The metal free copolymers are conjugatively-lmked with tunctionalized intramolecular charge transfer units, which exhibited prominent absorption band in the UV-vis region. These functionalized charge transfer units not only broadened the absorption spectrum, but also functioned as a bidentate ligand. Upon the complexation of rhenium(I) pentacarbonyl chloride, the absorption spectrum of the resulting polymers was further boardened, and the bandgap was reduced. The material design of this work has opened up a new approach in developing low bandgap metal-containing polymers as light harvesting materials. (Reprented Fig.) © 2010 WILEY-VCH Verlag GmbH & Co. KGaA. | ||||||
| Persistent Identifier | http://hdl.handle.net/10722/69800 | ||||||
| ISSN | 2023 Impact Factor: 4.2 2023 SCImago Journal Rankings: 1.056 | ||||||
| ISI Accession Number ID |
Funding Information: The project was supported by the Research Grants Council of the Hong Kong Special Administrative Region, China (project Nos. HKU 7008/07P and 7005/08P). Financial support from the University Development Fund, Strategic Research Theme and Small Project Fund (administrated by The University of Hong Kong) are also acknowledged. | ||||||
| References |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Mak, CSK | en_HK |
| dc.contributor.author | Cheung, WK | en_HK |
| dc.contributor.author | Leung, QY | en_HK |
| dc.contributor.author | Chan, WK | en_HK |
| dc.date.accessioned | 2010-09-06T06:16:57Z | - |
| dc.date.available | 2010-09-06T06:16:57Z | - |
| dc.date.issued | 2010 | en_HK |
| dc.identifier.citation | Macromolecular Rapid Communications, 2010, v. 31 n. 9-10, p. 875-882 | en_HK |
| dc.identifier.issn | 1022-1336 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/69800 | - |
| dc.description.abstract | Conjugated copolymers with novel low bandgap rhenium(I) complexes on the polymer mainchain are reported. The low bandgap metal-containing polymers were synthesized by Suzuki cross-coupling polycondensation or Stille coupling polymerization. The metal free copolymers are conjugatively-lmked with tunctionalized intramolecular charge transfer units, which exhibited prominent absorption band in the UV-vis region. These functionalized charge transfer units not only broadened the absorption spectrum, but also functioned as a bidentate ligand. Upon the complexation of rhenium(I) pentacarbonyl chloride, the absorption spectrum of the resulting polymers was further boardened, and the bandgap was reduced. The material design of this work has opened up a new approach in developing low bandgap metal-containing polymers as light harvesting materials. (Reprented Fig.) © 2010 WILEY-VCH Verlag GmbH & Co. KGaA. | en_HK |
| dc.language | eng | en_HK |
| dc.publisher | Wiley - V C H Verlag GmbH & Co KGaA. | en_HK |
| dc.relation.ispartof | Macromolecular Rapid Communications | en_HK |
| dc.subject | Conjugated polymer | en_HK |
| dc.subject | Low bandgap | en_HK |
| dc.subject | Metal-containing polymer | en_HK |
| dc.subject | Morphology | en_HK |
| dc.subject | Photovoltaic | en_HK |
| dc.subject | Rhenium(I) | en_HK |
| dc.title | Conjugated copolymers containing low bandgap rhenium(I) complexes | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1022-1336&volume=31&spage=&epage=&date=2010&atitle=Conjugated+Copolymers+Containing+Low+Bandgap+Rhenium(I)+Complexes | en_HK |
| dc.identifier.email | Mak, CSK: cskm@hkucc.hku.hk | en_HK |
| dc.identifier.email | Chan, WK: waichan@hku.hk | en_HK |
| dc.identifier.authority | Mak, CSK=rp00761 | en_HK |
| dc.identifier.authority | Chan, WK=rp00667 | en_HK |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/marc.200900890 | en_HK |
| dc.identifier.scopus | eid_2-s2.0-77952643584 | en_HK |
| dc.identifier.hkuros | 170070 | en_HK |
| dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-77952643584&selection=ref&src=s&origin=recordpage | en_HK |
| dc.identifier.volume | 31 | en_HK |
| dc.identifier.issue | 9-10 | en_HK |
| dc.identifier.spage | 875 | en_HK |
| dc.identifier.epage | 882 | en_HK |
| dc.identifier.eissn | 1521-3927 | - |
| dc.identifier.isi | WOS:000278436300014 | - |
| dc.publisher.place | Germany | en_HK |
| dc.identifier.scopusauthorid | Mak, CSK=8899597100 | en_HK |
| dc.identifier.scopusauthorid | Cheung, WK=36104019200 | en_HK |
| dc.identifier.scopusauthorid | Leung, QY=25650267500 | en_HK |
| dc.identifier.scopusauthorid | Chan, WK=13310083000 | en_HK |
| dc.identifier.issnl | 1022-1336 | - |