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Article: Synthesis, photophysics and electrochemistry of copper(I) diimine complexes containing thia-, selena- and tellura-crowns. A spectrochemical and luminescence ion probe for soft metal ions
Title | Synthesis, photophysics and electrochemistry of copper(I) diimine complexes containing thia-, selena- and tellura-crowns. A spectrochemical and luminescence ion probe for soft metal ions |
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Authors | |
Issue Date | 1998 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton |
Citation | Journal Of The Chemical Society - Dalton Transactions, 1998 n. 21, p. 3615-3621 How to Cite? |
Abstract | A series of copper(I) diimine complexes containing benzo-10-thia-15-crown-5, benzo-10-selena-15-crown-5, benzo-10-tellura-15-crown-5 and benzo-7,10,13-trithia-15-crown-5 moieties have been synthesized and characterized and their photophysics and electrochemistry studied. The encapsulation of soft metal ions by the cavity of the complexes has been investigated by electronic absorption and emission spectroscopy. The crystal structures of [Cu(PPh3)2(dic-S)]BF4 and [Cu(PPh3)2(dic-Se)]BF4 have been determined. |
Persistent Identifier | http://hdl.handle.net/10722/69861 |
ISSN | |
References |
DC Field | Value | Language |
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dc.contributor.author | Yam, VWW | en_HK |
dc.contributor.author | Pui, YL | en_HK |
dc.contributor.author | Li, WP | en_HK |
dc.contributor.author | Lo, KKW | en_HK |
dc.contributor.author | Cheung, KK | en_HK |
dc.date.accessioned | 2010-09-06T06:17:30Z | - |
dc.date.available | 2010-09-06T06:17:30Z | - |
dc.date.issued | 1998 | en_HK |
dc.identifier.citation | Journal Of The Chemical Society - Dalton Transactions, 1998 n. 21, p. 3615-3621 | en_HK |
dc.identifier.issn | 0300-9246 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69861 | - |
dc.description.abstract | A series of copper(I) diimine complexes containing benzo-10-thia-15-crown-5, benzo-10-selena-15-crown-5, benzo-10-tellura-15-crown-5 and benzo-7,10,13-trithia-15-crown-5 moieties have been synthesized and characterized and their photophysics and electrochemistry studied. The encapsulation of soft metal ions by the cavity of the complexes has been investigated by electronic absorption and emission spectroscopy. The crystal structures of [Cu(PPh3)2(dic-S)]BF4 and [Cu(PPh3)2(dic-Se)]BF4 have been determined. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton | en_HK |
dc.relation.ispartof | Journal of the Chemical Society - Dalton Transactions | en_HK |
dc.title | Synthesis, photophysics and electrochemistry of copper(I) diimine complexes containing thia-, selena- and tellura-crowns. A spectrochemical and luminescence ion probe for soft metal ions | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=&spage=3615&epage=2621&date=1998&atitle=Synthesis,+photophysics+and+electrochemistry+of+copper(I)+diimine+complexes+containing+thia-,+selena-+and+tellura-crowns.++A+spectrochemical+and+luminescence+ion+probe+for+soft+metal+ions | en_HK |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_HK |
dc.identifier.authority | Yam, VWW=rp00822 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/A806243I | - |
dc.identifier.scopus | eid_2-s2.0-33748465506 | en_HK |
dc.identifier.hkuros | 39866 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-33748465506&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.issue | 21 | en_HK |
dc.identifier.spage | 3615 | en_HK |
dc.identifier.epage | 3621 | en_HK |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_HK |
dc.identifier.scopusauthorid | Pui, YL=6507440586 | en_HK |
dc.identifier.scopusauthorid | Li, WP=24758839600 | en_HK |
dc.identifier.scopusauthorid | Lo, KKW=26032181200 | en_HK |
dc.identifier.scopusauthorid | Cheung, KK=7402406613 | en_HK |
dc.identifier.issnl | 0300-9246 | - |