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Article: A new self-assembled copper(I) complex of 2-thioxo-5H-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one showing three-dimensional supramolecular networks
Title | A new self-assembled copper(I) complex of 2-thioxo-5H-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one showing three-dimensional supramolecular networks |
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Authors | |
Keywords | Copper complexes Crystal structures Polymeric complexes Thione complexes |
Issue Date | 1999 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica |
Citation | Inorganica Chimica Acta, 1999, v. 292 n. 1, p. 117-120 How to Cite? |
Abstract | The synthesis and structural characterization of a supramolecular copper(I) complex of 2-thioxo-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one are described. The complex crystallized in the orthorhombic space group Pna21 with the cell dimensions a=12.9124(2), b=20.7944(2), c=4.4457(1) Å, V=1193.70(3) Å3 and Z=4. The structure was refined to a final agreement factor R=0.0295. The C6H4OS5Cu units are connected by bridging iodide atoms to form a ladder structure. The CuCu separation is 2.9884(9) Å, and the short SS and SI contacts interchain lead to a novel three-dimensional network. © 1999 Elsevier Science S.A. |
Persistent Identifier | http://hdl.handle.net/10722/69864 |
ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.386 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Zuo, JL | en_HK |
dc.contributor.author | Bai, JF | en_HK |
dc.contributor.author | Shen, Z | en_HK |
dc.contributor.author | You, XZ | en_HK |
dc.contributor.author | Fun, HK | en_HK |
dc.contributor.author | Chinnakali, K | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.date.accessioned | 2010-09-06T06:17:32Z | - |
dc.date.available | 2010-09-06T06:17:32Z | - |
dc.date.issued | 1999 | en_HK |
dc.identifier.citation | Inorganica Chimica Acta, 1999, v. 292 n. 1, p. 117-120 | en_HK |
dc.identifier.issn | 0020-1693 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/69864 | - |
dc.description.abstract | The synthesis and structural characterization of a supramolecular copper(I) complex of 2-thioxo-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one are described. The complex crystallized in the orthorhombic space group Pna21 with the cell dimensions a=12.9124(2), b=20.7944(2), c=4.4457(1) Å, V=1193.70(3) Å3 and Z=4. The structure was refined to a final agreement factor R=0.0295. The C6H4OS5Cu units are connected by bridging iodide atoms to form a ladder structure. The CuCu separation is 2.9884(9) Å, and the short SS and SI contacts interchain lead to a novel three-dimensional network. © 1999 Elsevier Science S.A. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica | en_HK |
dc.relation.ispartof | Inorganica Chimica Acta | en_HK |
dc.rights | Inorganica Chimica Acta. Copyright © Elsevier BV. | en_HK |
dc.subject | Copper complexes | en_HK |
dc.subject | Crystal structures | en_HK |
dc.subject | Polymeric complexes | en_HK |
dc.subject | Thione complexes | en_HK |
dc.title | A new self-assembled copper(I) complex of 2-thioxo-5H-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one showing three-dimensional supramolecular networks | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1693&volume=292&spage=117&epage=120&date=1999&atitle=A+new+self-assembled+copper(I)+complex+of+2-thioxo-5H-1,3-dithiolo[4,5-b][1,4]dithiepin-6(7H)-one+showing+three-dimensional+supramolecular+networks | en_HK |
dc.identifier.email | Che, CM:cmche@hku.hk | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/S0020-1693(99)00155-3 | - |
dc.identifier.scopus | eid_2-s2.0-0039442522 | en_HK |
dc.identifier.hkuros | 53167 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0039442522&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 292 | en_HK |
dc.identifier.issue | 1 | en_HK |
dc.identifier.spage | 117 | en_HK |
dc.identifier.epage | 120 | en_HK |
dc.identifier.isi | WOS:000082226700016 | - |
dc.publisher.place | Netherlands | en_HK |
dc.identifier.scopusauthorid | Zuo, JL=7202871908 | en_HK |
dc.identifier.scopusauthorid | Bai, JF=7403129290 | en_HK |
dc.identifier.scopusauthorid | Shen, Z=13606179000 | en_HK |
dc.identifier.scopusauthorid | You, XZ=36072101800 | en_HK |
dc.identifier.scopusauthorid | Fun, HK=34975048300 | en_HK |
dc.identifier.scopusauthorid | Chinnakali, K=7004369632 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.issnl | 0020-1693 | - |