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- Publisher Website: 10.1021/ol015722p
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Article: First enantioselective syntheses of (+)- and (-)-wilforonide by using chiral auxiliaries derived from the same chiral source
| Title | First enantioselective syntheses of (+)- and (-)-wilforonide by using chiral auxiliaries derived from the same chiral source |
|---|---|
| Authors | |
| Issue Date | 2001 |
| Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html |
| Citation | Organic Letters, 2001, v. 3 n. 12, p. 1785-1788 How to Cite? |
| Abstract | (formula presented) The first enantioselective syntheses of both (+)-wilforonide (>98% ee) and (-)-wilforonide (>98% ee) have been accomplished by employing chiral auxiliaries derived from the same chiral source, (R)-pulegone. The bicyclic skeleton of wilforonide was constructed by using Mn(III)-based oxidative radical cyclization reactions of chiral β-keto esters. The absolute configuration of natural wilforonide has been established to be (5aR,9aR). |
| Persistent Identifier | http://hdl.handle.net/10722/69911 |
| ISSN | 2021 Impact Factor: 6.072 2020 SCImago Journal Rankings: 1.940 |
| ISI Accession Number ID | |
| References |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Yang, D | en_HK |
| dc.contributor.author | Xu, M | en_HK |
| dc.date.accessioned | 2010-09-06T06:17:58Z | - |
| dc.date.available | 2010-09-06T06:17:58Z | - |
| dc.date.issued | 2001 | en_HK |
| dc.identifier.citation | Organic Letters, 2001, v. 3 n. 12, p. 1785-1788 | en_HK |
| dc.identifier.issn | 1523-7060 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/69911 | - |
| dc.description.abstract | (formula presented) The first enantioselective syntheses of both (+)-wilforonide (>98% ee) and (-)-wilforonide (>98% ee) have been accomplished by employing chiral auxiliaries derived from the same chiral source, (R)-pulegone. The bicyclic skeleton of wilforonide was constructed by using Mn(III)-based oxidative radical cyclization reactions of chiral β-keto esters. The absolute configuration of natural wilforonide has been established to be (5aR,9aR). | en_HK |
| dc.language | eng | en_HK |
| dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html | en_HK |
| dc.relation.ispartof | Organic Letters | en_HK |
| dc.title | First enantioselective syntheses of (+)- and (-)-wilforonide by using chiral auxiliaries derived from the same chiral source | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1523-7060&volume=3&issue=12&spage=1785&epage=1788&date=2001&atitle=First+Enantioselective+Syntheses+of+(+)-+and+(-)-Wilforonide+by+Using+Chiral+Auxiliaries+Derived+from+the+Same+Chiral+Source | en_HK |
| dc.identifier.email | Yang, D:yangdan@hku.hk | en_HK |
| dc.identifier.authority | Yang, D=rp00825 | en_HK |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/ol015722p | en_HK |
| dc.identifier.scopus | eid_2-s2.0-0035859356 | en_HK |
| dc.identifier.hkuros | 58726 | en_HK |
| dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0035859356&selection=ref&src=s&origin=recordpage | en_HK |
| dc.identifier.volume | 3 | en_HK |
| dc.identifier.issue | 12 | en_HK |
| dc.identifier.spage | 1785 | en_HK |
| dc.identifier.epage | 1788 | en_HK |
| dc.identifier.isi | WOS:000169247100001 | - |
| dc.publisher.place | United States | en_HK |
| dc.identifier.scopusauthorid | Yang, D=7404800756 | en_HK |
| dc.identifier.scopusauthorid | Xu, M=15729771700 | en_HK |
| dc.identifier.issnl | 1523-7052 | - |