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Article: Reactivity of chiral diiminodiphosphine ligands towards PdCl2(PHCN)2: synthesis and crystal structures of two unexpected dinuclear palladium(II) complexes

TitleReactivity of chiral diiminodiphosphine ligands towards PdCl2(PHCN)2: synthesis and crystal structures of two unexpected dinuclear palladium(II) complexes
Authors
Issue Date2000
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal of the Chemical Society Dalton Transactions, 2000, p. 1397-1398 How to Cite?
AbstractThe interaction of PdCl2(PhCN)2 with (S )-N,N ′-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-1,1′-binaphthylene (S )-L1 and (S,S ′)-N,N ′-bis[2-(diphenylphosphino)-benzylidene]-1,2-diimino-1,2-diphenylethane (S,S ′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH[double bond, length half m-dash]N]}21 and the dinuclear complex {cis-PdCl2[2-(Ph2P)C6H4CH[double bond, length half m-dash] NCH(Ph)CH(C6H4PPh2-2)[double bond, length half m-dash]NC6H4(PPh2)-2]PdCl}{Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.
Persistent Identifierhttp://hdl.handle.net/10722/70051
ISSN
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWong, WKen_HK
dc.contributor.authorZhang, LLen_HK
dc.contributor.authorChen, Yen_HK
dc.contributor.authorWong, WYen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorXue, Fen_HK
dc.contributor.authorMak, TCWen_HK
dc.date.accessioned2010-09-06T06:19:15Z-
dc.date.available2010-09-06T06:19:15Z-
dc.date.issued2000en_HK
dc.identifier.citationJournal of the Chemical Society Dalton Transactions, 2000, p. 1397-1398en_HK
dc.identifier.issn1472-7773en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70051-
dc.description.abstractThe interaction of PdCl2(PhCN)2 with (S )-N,N ′-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-1,1′-binaphthylene (S )-L1 and (S,S ′)-N,N ′-bis[2-(diphenylphosphino)-benzylidene]-1,2-diimino-1,2-diphenylethane (S,S ′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH[double bond, length half m-dash]N]}21 and the dinuclear complex {cis-PdCl2[2-(Ph2P)C6H4CH[double bond, length half m-dash] NCH(Ph)CH(C6H4PPh2-2)[double bond, length half m-dash]NC6H4(PPh2)-2]PdCl}{Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.-
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofJournal of the Chemical Society Dalton Transactionsen_HK
dc.titleReactivity of chiral diiminodiphosphine ligands towards PdCl2(PHCN)2: synthesis and crystal structures of two unexpected dinuclear palladium(II) complexesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=&spage=1397&epage=1398&date=2000&atitle=Reactivity+of+chiral+diiminodiphosphine+ligands+towards+PdCl2(PHCN)2:+synthesis+and+crystal+structures+of+two+unexpected+dinuclear+palladium(II)+complexesen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1039/B001245I-
dc.identifier.scopuseid_2-s2.0-0002576733-
dc.identifier.hkuros53875en_HK
dc.identifier.isiWOS:000086710100003-
dc.identifier.issnl1364-5447-

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