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- Publisher Website: 10.1016/0022-328X(95)05463-Y
- Scopus: eid_2-s2.0-0000532924
- WOS: WOS:A1995RD76900022
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Article: Synthesis and crystal structure of [(η5:η5-C5H4PPh2)Tl]∞ and the divalent ytterbium derivative [(η5-C5H4PPh2)2Yb(DME)]
Title | Synthesis and crystal structure of [(η5:η5-C5H4PPh2)Tl]∞ and the divalent ytterbium derivative [(η5-C5H4PPh2)2Yb(DME)] |
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Authors | |
Keywords | Thallium Ytterbium Cyclopentadienyl Crystal structure |
Issue Date | 1995 |
Publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem |
Citation | Journal of Organometallic Chemistry, 1995, v. 495 n. 1-2, p. 203-208 How to Cite? |
Abstract | The complex [(diphenylphosphino)cyclopentadienyl]thallium [(η5:η5-C5H4PPh2)Tl]∞ (1) and the divalent ytterbium compound [(η5-C5H4PPh2)2Yb(DME)] (2) (DME = dimethoxyethane) made from it have been synthesized and characterized by IR, 1H NMR and 31P NMR spectroscopy and X-ray diffraction studies. In the crystal 1, polymeric zigzag chains of alternating thallium ions and cyclopentadienyl rings, form, with the neighboring chains were connected by the weak interactions between phosphorus and thallium atoms. In contrast, 2 is a neutral monomer with two dangling phosphorus atoms. |
Persistent Identifier | http://hdl.handle.net/10722/70230 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Lin, G | en_HK |
dc.contributor.author | Wong, WT | en_HK |
dc.date.accessioned | 2010-09-06T06:20:56Z | - |
dc.date.available | 2010-09-06T06:20:56Z | - |
dc.date.issued | 1995 | en_HK |
dc.identifier.citation | Journal of Organometallic Chemistry, 1995, v. 495 n. 1-2, p. 203-208 | en_HK |
dc.identifier.issn | 0022-328X | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/70230 | - |
dc.description.abstract | The complex [(diphenylphosphino)cyclopentadienyl]thallium [(η5:η5-C5H4PPh2)Tl]∞ (1) and the divalent ytterbium compound [(η5-C5H4PPh2)2Yb(DME)] (2) (DME = dimethoxyethane) made from it have been synthesized and characterized by IR, 1H NMR and 31P NMR spectroscopy and X-ray diffraction studies. In the crystal 1, polymeric zigzag chains of alternating thallium ions and cyclopentadienyl rings, form, with the neighboring chains were connected by the weak interactions between phosphorus and thallium atoms. In contrast, 2 is a neutral monomer with two dangling phosphorus atoms. | - |
dc.language | eng | en_HK |
dc.publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem | en_HK |
dc.relation.ispartof | Journal of Organometallic Chemistry | en_HK |
dc.subject | Thallium | - |
dc.subject | Ytterbium | - |
dc.subject | Cyclopentadienyl | - |
dc.subject | Crystal structure | - |
dc.title | Synthesis and crystal structure of [(η5:η5-C5H4PPh2)Tl]∞ and the divalent ytterbium derivative [(η5-C5H4PPh2)2Yb(DME)] | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=495 Nos1-2&spage=203&epage=208&date=1995&atitle=Synthesis+and+X-ray+crystal+structures+of+[(h5:h5-C5H4PPh2)Tl]++and+its+divalent+ytterbium+derivative+of+[(h5-C5H4PPh2)2Yb(DME)] | en_HK |
dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
dc.identifier.authority | Wong, WT=rp00811 | en_HK |
dc.identifier.doi | 10.1016/0022-328X(95)05463-Y | - |
dc.identifier.scopus | eid_2-s2.0-0000532924 | - |
dc.identifier.hkuros | 14575 | en_HK |
dc.identifier.volume | 495 | - |
dc.identifier.issue | 1-2 | - |
dc.identifier.spage | 203 | - |
dc.identifier.epage | 208 | - |
dc.identifier.isi | WOS:A1995RD76900022 | - |
dc.publisher.place | Switzerland | - |
dc.identifier.issnl | 0022-328X | - |