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- Publisher Website: 10.1021/ic9021068
- Scopus: eid_2-s2.0-77649109589
- PMID: 20099846
- WOS: WOS:000274626200033
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Article: Design, synthesis, photophysics, and ion-binding studies of a ditopic receptor based on goid(i) phosphine thiolate complex functionalized with crown ether and urea binding units
| Title | Design, synthesis, photophysics, and ion-binding studies of a ditopic receptor based on goid(i) phosphine thiolate complex functionalized with crown ether and urea binding units | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| Authors | |||||||||
| Issue Date | 2010 | ||||||||
| Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | ||||||||
| Citation | Inorganic Chemistry, 2010, v. 49 n. 5, p. 2273-2279 How to Cite? | ||||||||
| Abstract | A ditopic receptor based on gold(l) phosphine thiolate complex [(B15C5Ph2P)Au(SC6H4NHCONHC6H 5)] (1) together with a related crown-free analogue, [(Ph 3P)Au(SC6H4NHCONHC6H5)] (2), have been designed and synthesized and their photophysical properties studied. Complex 1 featured both a benzo-15-crown-5 cation-binding unit in the auxiliary phosphine ligand and a urea-functionalized thiolate as an anion receptor moiety. The anion- and cation-binding study, salt extraction ability, as well as the cooperativity have been studied using 1H NMR and ESI-MS techniques. © 2010 American Chemical Society. | ||||||||
| Persistent Identifier | http://hdl.handle.net/10722/70307 | ||||||||
| ISSN | 2021 Impact Factor: 5.436 2020 SCImago Journal Rankings: 1.348 | ||||||||
| ISI Accession Number ID |
Funding Information: V.W.-W.Y. acknowledges the support from The University of Hong Kong under the Distinguished Research Achievement Award Scheme and the URC Strategic Research Theme on Molecular Materials. This work has been supported by a General Research Fund (GRF) grant from the Research Grants Council of Hong Kong Special Administrative Region, P. R. China (HKU 7050/08P). X.H. acknowledges the receipt of a postgraduate studentship, administered by The University of Hong Kong. | ||||||||
| References |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | He, X | en_HK |
| dc.contributor.author | Yam, VWW | en_HK |
| dc.date.accessioned | 2010-09-06T06:21:38Z | - |
| dc.date.available | 2010-09-06T06:21:38Z | - |
| dc.date.issued | 2010 | en_HK |
| dc.identifier.citation | Inorganic Chemistry, 2010, v. 49 n. 5, p. 2273-2279 | en_HK |
| dc.identifier.issn | 0020-1669 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/70307 | - |
| dc.description.abstract | A ditopic receptor based on gold(l) phosphine thiolate complex [(B15C5Ph2P)Au(SC6H4NHCONHC6H 5)] (1) together with a related crown-free analogue, [(Ph 3P)Au(SC6H4NHCONHC6H5)] (2), have been designed and synthesized and their photophysical properties studied. Complex 1 featured both a benzo-15-crown-5 cation-binding unit in the auxiliary phosphine ligand and a urea-functionalized thiolate as an anion receptor moiety. The anion- and cation-binding study, salt extraction ability, as well as the cooperativity have been studied using 1H NMR and ESI-MS techniques. © 2010 American Chemical Society. | en_HK |
| dc.language | eng | en_HK |
| dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | en_HK |
| dc.relation.ispartof | Inorganic Chemistry | en_HK |
| dc.title | Design, synthesis, photophysics, and ion-binding studies of a ditopic receptor based on goid(i) phosphine thiolate complex functionalized with crown ether and urea binding units | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=49&issue=5&spage=2273&epage=2279&date=2010&atitle=Design,+synthesis,+photophysics,+and+ion-binding+studies+of+a+ditopic+receptor+based+on+gold(I)+phosphine+thiolate+complex+functionalized+with+crown+ether+and+urea+binding+units | en_HK |
| dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_HK |
| dc.identifier.authority | Yam, VWW=rp00822 | en_HK |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1021/ic9021068 | en_HK |
| dc.identifier.pmid | 20099846 | - |
| dc.identifier.scopus | eid_2-s2.0-77649109589 | en_HK |
| dc.identifier.hkuros | 168995 | en_HK |
| dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-77649109589&selection=ref&src=s&origin=recordpage | en_HK |
| dc.identifier.volume | 49 | en_HK |
| dc.identifier.issue | 5 | en_HK |
| dc.identifier.spage | 2273 | en_HK |
| dc.identifier.epage | 2279 | en_HK |
| dc.identifier.isi | WOS:000274626200033 | - |
| dc.publisher.place | United States | en_HK |
| dc.identifier.scopusauthorid | He, X=7404409089 | en_HK |
| dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_HK |
| dc.identifier.issnl | 0020-1669 | - |